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二次导数伏安法同时测定食品中苋菜红、胭脂红色素含量 被引量:5

SIMULTANEOUS DETERMINATION OF AMARANTH AND CARMINE IN FOOD BY SECOND DERIVATIVE VOLTAMMETRY
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摘要 用线性扫描吸附伏安法研究了Tris-醋酸底液中(pH8.7),食用色素苋菜红,胭脂红在悬汞电极上的伏安特性,两色素分别在-0.51V和-0.67V(vs.SCE)产生强吸附还原峰,导数峰电流与其浓度分别在5.0×10(-10)~5.0×10(-7)及5.0×10(-9)~1.0×10(-7)mol/L范围内呈良好线性关系,本法可不经分离直接测定食品、药物胶囊中两色素各自的含量. The behaviour of the amaranth and carmine,at a hanging mercury electrode,has been investigated in Tris-HAc solution(pH8. 7)by using linear potential sweep voltammetry. The peak potential were obtained at - 0. 51 V(SCE)for 5. 0 × 10 ̄(-1) ~ 5. 0 × 10 ̄(-7) and 5. 0 ×10 ̄(-9) ~ 1. 0 × 10 ̄(-7) mol/L carmine. The derivative peak currents were directly proportional to the concentration of amaranth and carmine over the range of 5. 0 × 10 ̄(-10) ~ 5. 0 × 10 ̄(-7)and 5. 0 × 10 ̄(-9) ~ 1. 0 × 10 ̄(-7)mol/L respectively. this method can be used for the determination of amaranth and carmine in food or some tablets coating without deseparation.
出处 《山东大学学报(自然科学版)》 CSCD 1994年第1期75-78,共4页 Journal of Shandong University(Natural Science Edition)
关键词 吸附伏安法 苋菜红 胭脂红 食品 second derivative voltammetry amaranth carmine
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参考文献3

  • 1柯以侃,化学世界,1991年,4卷,164页
  • 2陈怡婷,分析化学,1988年,16卷,1期,9页
  • 3张雅青,药物分析杂志,1985年,5卷,5期,299页

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