摘要
主要应用电化学方法研究了苯胺及其电化学聚合产物─—聚苯胺的循环伏安曲线，同时讨论了苯胺的存在对４－氨基二苯胺循环伏安曲线的影响。结果表明：随着苯胺聚合的进行，聚苯胺同时发生降解；苯胺电化学聚合按“白催化机理”进行。
The cyclic voltammetry curves of aniline and its electrochenmical polymerization prod-uc──polyaniline were discussed mainly using electrochemical techniques. The effect of presence ofaniline on the cyclic voltammetry curves of para-aminodiphenylamine was investigated. The experi-ments indicated that the degradation of polyaniline occurs as the polymerization of aniline proceeds andthe autocatalytic mechanism is reasoiiable for the electrochemical polymeriration of aniline.
出处
《合成化学》
CAS
CSCD
1994年第3期258-262,共5页
Chinese Journal of Synthetic Chemistry
关键词
苯胺
聚电化学聚合
反应机理
Aniline , Electrochemical polymerisation, Mechanism, Cyclic voltammetry curve.
