摘要
二茂铁基化合物因具有独特的氧化还原、电、光、磁和催化性能,而被广泛研究与应用.电子自旋共振(ESR)技术是观察物质顺磁性最直接的手段,在研究二茂铁基化合物的电子结构、电子转移和分子间相互作用等方面具有独特的优势.ESR技术还具有灵敏度高、样品处理简单、直接检测不破坏样品等优点.该文综述了二茂铁基化合物的ESR研究进展.
Ferrocenyl compounds were widely used and extensively studied due to theirexcellent thermal, redox, electronic, optic, magnetic and catalytic properties. Electron spinresonance （ESR） is a method that can be used to study paramagnetic behaviors, electronicstructure, electron transfer and molecular interactions of ferrocenyl compounds. Inaddition, ESR possesses advantages such as high sensitivity, easy sample treatment andnondestructive testing. This article reviewed recent progresses in ESR studies on ferrocenylcompounds.
出处
《波谱学杂志》
CAS
CSCD
北大核心
2016年第3期491-501,共11页
Chinese Journal of Magnetic Resonance
基金
国家自然科学基金资助项目(21372200
21472168)
