期刊文献+

固相反应烧结法制备CCTO陶瓷 被引量:7

CaCu_3Ti_4O_(12) ceramics prepared by solid state reaction sinter
在线阅读 下载PDF
导出
摘要 采用固相反应烧结法制备了CaCu3Ti4O12(CCTO)陶瓷,研究了其烧结性能、结构和介电性能。在1120℃烧结即可获得单相CCTO致密陶瓷,其收缩率高达22.3%。εr随着烧结温度升高而明显增大,且具有明显的频率敏感性,利用复阻抗谱分析了CCTO陶瓷的介电特性。于1120℃,烧结3h制备的CCTO陶瓷的εr为3005(室温,1kHz)。 CaCu3Ti4O12 (CCTO) ceramics were prepared by solid-state reaction sinter. The sintering behavior, crystal structure and dielectric properties of CCTO ceramics were investigated together with frequency and temperature dependence of dielectric properties. The single phase dense ceramics CCTO was sintered at 1 120 ℃ for 3 h, which the shrinkage reached 22.3%. Dielectric constant obviously increase with increase of sintering temperature and is strongly sensitive to frequency. These dielectric behaviors are analyzed by impedance spectra. The CCTO ceramics are obtained with dielectric constant of 3 005 (at room temperature and 1 kHz).
出处 《电子元件与材料》 CAS CSCD 北大核心 2007年第11期20-21,25,共3页 Electronic Components And Materials
基金 福建省先进陶瓷技术重大专项资助项目(2005HZ02-3) 福州大学人才基金资助项目(XJY-0413) 福建省青年科技人才创新基金资助项目(2005J012)
关键词 无机非金属材料 钙钛矿 介电性能 固相反应烧结 CACU3TI4O12 non-metallic inorganic material perovskite dielectric properties solid-state reaction sinter CaCu3Ti4O12
  • 相关文献

参考文献11

  • 1Subramanian M A, Li D, Duan N, et al. High dielectric constant in mCu3Wi4O12 and ACu3Ti3FeO12 phases [J]. Solid State Chem, 2000, 151: 323-325.
  • 2Ramirez A E Subramanian M A, Gardel M, et al. Giant Dielectric constant response in a Copper -Titanate [J]. Solid State Commun, 2000, 115: 217- 220.
  • 3Subramanian M A, Sleight A W. ACu3Ti4O12 and ACu3Ru4O12 perovskites: high dielectric constants and valence degeneracy [J]. Solid State Sci, 2002, 4: 347-351.
  • 4Homes C C, Vogt T, Shapiro S M, et al. Optical response of high-dielectric-constant perovskite-related oxide [J]. Science, 2001, 121: 625-629.
  • 5Chakravarty D, Singh E Singh S, et al. Electrical conduction behavior of high dielectric constant perovskite oxide LaxCa1-3x/2Ti4O12 [J]. J Alloys Comp, 438: 253-257.
  • 6Choudhary R N P, Bhunia B. Structural. dielectric and electrical propreties ofACu3Ti4O12(A=Ca, Sr and Ba) [J]. Mater Sci, 2002,37:5177 -8182,
  • 7Ramirez M A,, Bueno P R, Varela J A, et al. Non-ohmic and dielectric properties of Ca2Cu2Ti4O12 polycrystlline system [J]. Appl Phys Lett, 2006, 89: 212102.
  • 8Sinclair D C, Adams T B, Morrison F D, et al. CCTO: One-step in-internal barrier layer capacitor [J]. Appl Phys Lett, 2002, 80(12): 2153-2155.
  • 9Adams T B, Sinclair D C, West A R. Giant barrier layer capacitance effects in CCTO ceramics [J]. Adv Mater, 2002 14: 1321-1323
  • 10倪维庆,俞建长,郑兴华,梁炳亮.烧成工艺对CaCu_3Ti_4O_(12)陶瓷介电性能的影响[J].电子元件与材料,2006,25(10):26-29. 被引量:8

二级参考文献15

  • 1周小莉,杜丕一.阻挡层电容对ACu_3Ti_4O_(12)巨介电性能的影响研究[J].物理学报,2005,54(1):354-358. 被引量:21
  • 2周小莉,杜丕一.CaCu_3Ti_4O_(12)的制备及其对巨介电性能的影响[J].无机材料学报,2005,20(2):484-488. 被引量:20
  • 3Subramanian M A, Li D, Duan N, et al. High dielectric constant in ACu3Ti4O12 and ACu3Ti3FeO12 phases [J]. Solid State Chem, 2000, 151:323 -325
  • 4Ramirez A P, Subramanian M A, Gardel M, et al. Giant dielectric constant response in a copper -titanate[J]. Solid State Commun, 2000,115: 217-220.
  • 5Subramanian M A, Sleight A W. ACu3Ti4Oi2 and ACu3Ru4O12 perovskites: high dielectric constants and valence degeneracy[J]. Solid State Sci, 2002,4:347-351.
  • 6Homes C C, Vogt T, Shapiro S M, et al. Optical response of high-dielectric-constant perovskite-related oxide[J]. Science, 2001, 121:625 - 629.
  • 7Moussa S M, Kennedy B J. Structural studies of the distorted perovskite Ca0.25Cu0.75TiO3 [J]. Mater Res Bull, 2001, 36: 2525-2529.
  • 8Choudhary R N P, Bhunia B. Structural, .dielectric and electrical propreties of ACu3ThO12(A=Ca, Sr and Ba)[J]. Mater Sci, 2002, 37:5177-8182.
  • 9Jha P, Arora P, Ganguli A K. Polymeric citrate precursor route to the synthesis of the high dielectric constant oxide, CCTO [J]. Mater Lett,2003, 57: 2443-2446.
  • 10Sinclair D C, Adams T B, Morrison F D, et al. CCTO: One-step in-internal barrier layer capacitor[J]. Appl Phys Lett, 2002, 80(12): 2153-2155.

共引文献7

同被引文献75

引证文献7

二级引证文献24

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部