摘要
本文拟定了荧光法测定铜的新方法,详细研究了Cu-硫胺素体系测铜的最佳条件,该法简便、选择性好,灵敏度高,检测限可达0.25ng/ml,用于人发和纯铝样品中铜含量的测定,结果令人满意。
A new fluorimetric method for the determination of micro-amounts of copper was set up, based on the oxidation of thiamine into highly fluorescent thiochrome by Cu^(2-) in base medium. The fluorescence intensity was linear with the concentration of copper from 0. 006 to 10 ng/25ml. The relative standard deviation was 3. 5 % and the detection limit was 0. 25 ng/ml (3σ). The method has been used to determine copper in pure aluminium and hair samples.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1994年第5期472-474,共3页
Chinese Journal of Analytical Chemistry
