摘要
以72.8%的产率合成了双水杨醛缩乙二胺合铜配合物[Cu(Salen)],用正交试验法考察了该配合物对安息香的空气氧化反应的催化作用。实验发现,在水杨醛乙二胺合铜配合物的催化下,安息香经空气氧化生成苯偶酰的产率可达87.9%。
N,N′-Bis(salicylidene)ethylenediamino copper[Cu(Salen)]was synthesized with a yield of (72.8%;) Oxidation of benzoin in air atmosphere catalyzed by Cu(Salen) was investigated with the method of orthogonal design. The yield of benzil was 87.9%.
出处
《化学世界》
CAS
CSCD
北大核心
2004年第5期233-234,250,共3页
Chemical World
