摘要
首次报道了新型Ｓｃｈｉｆ碱类配体双［Ｎ，Ｎ－亚烃基－２，２－（苯亚甲基）二（３，４－二甲基吡咯－５－醛缩亚胺）］和双［Ｎ，Ｎ－（１，２－亚乙基）－２，２－（４－甲氧基苯亚甲基）二（３，４－二甲基吡咯－５－醛缩亚胺）］及其双锰配合物的合成方法、光谱特征及用配合物催化ＰｈＩＯ单加氧化环己烷反应的研究．
This paper first reports the syntheses and spectral character of bis[ N,N alkylene 2,2 (phenylmethylene)bis(3,4 dimethylpyrrole 5 aldimine)](alkylenes: 1,3 propylene; 1,4 butylene; 1,2 phenylene; 4 methyl 1,2 phenylene), bis[ N,N (1,2 ethylene) 2,2 (4 methoxyphenylmethylene) bis(3,4 dimethylpyrrole 5 aldimine)] and their dimanganese(Ⅱ) complexes as well as the biomimetic catalytic properties of the complexes for the monooxygenation of cyclohexane with PhIO.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1998年第7期1065-1069,共5页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
