摘要
2-羟基吡啶、希土高氯酸盐和乙酸钴在乙腈中反应,制备了九配位化合物[Tb(CH_3COO)_3·2H_2O]_2该晶体为三斜晶系,P^(?)空间群,其晶胞参数为a=8.870(4)(?),b=9.247(1)(?),c=10.586(1)(?),α=65.13(1)°,β=64.43(2)°,γ=62.16(4)°,V=665.97(?)~3,Z=1,F(000)=394。测定了配合物的红外光谱。讨论了它的生成机制。
The title complex was synthesized by reaction of 2-hydroxypyridine, Tb(ClO4)3 ·6H2O and Co(CH3COO)2·2H2O in CH3CN solution. The crystal of [Tb(CH3COO)3·2H2O]2 belongs to triclinic with space group P1. The unit cell parameters are a = 8.870(4)A, b = 9.247(1) A , c=10.586(1)A, α = 65.13(1)°?, β = 64.43(2)°, r = 62.16(4)A, V=665.97A3, Z=1,F(000) = 394. The Tb atoms are connected through one pair of u2-bridging carboxylic acid groups to form a dimer molecule. Each Tb atom is coordinated by nine oxygen atoms. The polyhedron takes are onecapped square antiprism arrangement.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1992年第2期164-167,共4页
Chinese Journal of Inorganic Chemistry
关键词
醋酸盐
晶体结构
铽配合物
terbium acetate complex crystal structure
