摘要
２－羟基吡啶、Ｎｉ（ＣＨ３ＣＯＯ）２和Ｔｂ（ＣｌＯ４）３在乙腈中反应，得到（Ｔｂ（ＣＨ３ＣＯＯ）３］ｎ，并测定了它的晶体结构．［Ｔｂ（ＣＨ３ＣＯＯ）３］ｎ的晶体为三斜晶系，Ｐ－１空间群，ａ＝７．９１３（１）Ａ，ｂ＝８３３０（１）Ａ，ｃ＝１１．５７３３（２）Ａ，ａ＝７０．２９（１）°，β＝７２．２３（１）°，ｒ＝６５．０３（１）°；［Ｔｂ（ＣＨ３ＣＯＯ）３］ｎ为六配位畸变八面体构型，整个分子是长链多聚结构．
The title complex was synthesized by reaction of 2-hydroxypyridine, Ni(CHCOO)2 and Tb(ClO4)3, in CH3CN solution. The x-ray diffraction analysis shows that the crystal is a triclinic space group P-1 with a= 7. 913(1) A,b= 8. 330(1) A,c = 11. 573 (2 )A,a= 70. 29(1 )°,β = 72. 23 (1 )°, r= 65. 03 (1 )°, [Tb (CH3COO )3 ]N. is of six-coordinated octahedral geometryand of long-chain polymers.
出处
《天津大学学报》
EI
CAS
CSCD
1995年第5期632-635,共4页
Journal of Tianjin University(Science and Technology)
基金
国家自然科学基金
关键词
铽
乙酸根
配合物
晶体结构
合成
terbium, acetate, complex, crystal structure
