摘要
该文介绍以六硝基联苄(HNBB)为中间体,用梯恩梯(TNT)为原料,分两步合成六硝基艺(HNS)的工艺路线,给出了六硝基联苄氧化成六硝基(艹氐)的最佳工艺条件。文中详细讨论了反应母液循环套用对六硝基(艹氐)的得率和质量的影响,并用核磁共振谱(NMR)研究了水对反应的影响。
The technological route of the synthesis of HNS in two steps byraw material TNT through intermediate HNBB is introduced. The best techno-logical condition in which HNBB is oxidized into HNS is given. The effect ofthe reacting solvent reused cyclically on the yield and quality of HNS is dis-cussed. The effect of water on the reaction is studied by NMR.
