摘要
研究了以六硝基联苄（ＨＮＢＢ）为中间体，用梯恩梯（ＴＮＴ）为起始原料，分两步合成耐热炸药六硝基Ⅰ型（ＨＮＳ－Ⅰ）或六硝基Ⅱ型（ＨＮＳ－Ⅱ）的新方法。该方法由ＨＮＢＢ可直接合成ＨＮＳ－Ⅱ，由ＴＮＴ制造ＨＮＳ－Ⅰ的，总得率大于６５％，制造ＨＮＳ－Ⅱ总得率大于５９％。文中给出了反应的最佳工艺条件，讨论了溶剂对反应的影响。
A new method for synthsising a heatresistant explosive HNS-Ⅰor HNS-Ⅱ in two steps by raw material TNT through intermediate HNBB is studied in this article. HNS-Ⅱ can be prepared directly from HNBB in this method.The overall vield based on TNT is greater than 65%for HNs-Ⅰ,and is greater than 59%for HNS- Ⅱ.The best technological condition of synthetic reaction isgiven. The solvent effect on svnthetic reaction is discussed.
出处
《南京理工大学学报》
CAS
CSCD
1994年第5期8-11,共4页
Journal of Nanjing University of Science and Technology
关键词
耐热炸药
合成
六硝基芪
HNS-1
heat-resistant explosive, synthesis,manufacture,solvent effect
