摘要
本文提出了传质时间的新概念,并用于推导超微盘电极上同时控制包括Nernst扩散、对流扩散、化学反应和电极反应的稳态伏安曲线方程式,对电流、电位的性质进行了讨论。
In this paper, a new concept of mass transfer time is presented, by which the general equations of steady-state voltammetric curves simultaneously controlled by the Nernst diffusion, convection diffusion, charge transfer rate and chemical reaction at ultramicrodisk electrode are described. The behaviour of current-potential curve is discussed.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1992年第3期315-319,共5页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
超微盘电极
传质时间
伏安法
General equation of steady-state voltammetric curve, Ultramicrodisk electrode, Mass transfer time
