摘要
本文报道超微盘电极上双电位阶跃计时电流和计时库仑法理论,用自制的微机多功能电分析仪及亚铁氰化钾、氯化钾体系进行验证,实验结果与理论相符合.
This paper presents the theoretical relations for the chronoamperometric and Chronocoulometric response to a double potential step for a simple electrode reaction at an ultramicrodisk electrode. The experimental investigation employs the oxidation of K_4Fe(CN)_6 in the presence of KCI at platinum ultramicrodisk electrode with radius 10μm, and a general purpose microcomputer-based instrumentation used in this work was made in our laboratory by ourselves. The experimental results were found to agree with the theory.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
1992年第9期888-894,共7页
Acta Chimica Sinica
基金
高等学校博士学科点专项科研基金
