摘要
合成20种新的N-异丙基-S-丙基-N′-取代-N′-苯磺酰基硫(醇)代磷酰二胺酯化合物Ⅰ、Ⅱ。合成Ⅰ时,还分离出3种新的环状磷酰二胺酯内酯化合物Ⅲ,经~1HNMR、元素分析及MS证明了它们的结构。初步电生理测试表明,Ⅰ、Ⅱ类化合物对果蝇幼虫种经通道具有较好的阻断作用。
Twenty new N-isopropyl-S-propyl-N' -substitutent-N ' -benzene sulfonyl phospho-rothiodiamidoates Ⅰ,Ⅱ were synthesized; a cyclo phosphorodiamidoates ( Ⅲ ) formed as the byproduct during the reaction; their structures were confirmed by 1H NMR, elemental analysis or MS, the preliminary bioassay shows that these new compounds have a remarkable insecticidal ac-tivitives.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1992年第2期191-194,共4页
Chemical Journal of Chinese Universities
关键词
苯磺酰基
硫代磷酰
二胺酯
杀虫剂
S-Propylphosphoryldichloride, Benzenesulfonyl phosphorothiodiamidoate, Bioassay