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Organic solar cells based on molecular perylene diimides-type nonfullerene acceptors:achievements,challenges and the future

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摘要 Perylene-diimide(PDI)-based NFA could be synthesized via a few steps with high yields,and exhibit outstanding chemical robustness and photostability,which is suitable for the commercialization of organic solar cells(OSCs).Nowadays,the power conversion efficiency(PCE)of PDI-based OSCs has exceeded 11%and run into the bottleneck.It is time to summarize the latest achievements and find the clue to overcome the challenges for further improving the PCE of PDI-based OSCs.In this review,we summarize the latest achievements in PDI-based OSCs and highlight those potential strategies for further improving the photovoltaic performance of PDI-based OSCs,including fine-tuning the stacking behaviors and absorption spectra of PDI-based NFAs and the developments of narrow bandgap donor materials which are compatible with PDI-based NFAs.New record of PCE is anticipated and new application of PDI-based OSCs worths exploring.
出处 《Science China Chemistry》 2025年第8期3359-3375,共17页 中国科学(化学英文版)
基金 supported by the National Natural Science Foundation of China(52273195,51973169) the Young Top-notch Talent Cultivation Program of Hubei Province the Natural Science Foundation of Hubei Province(2022CFB097) the Innovation Fund of Hubei Key Laboratory of Plasma Chemistry and Advanced Materials the Graduate Innovative Fund of Wuhan Institute of Technology(CX2023064)。
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