摘要
由CO2-氧化苯乙烯(StO)配位催化共聚制得脂肪族聚碳酸苯亚乙酯,并用 IR、1HNMR和 DSC等进行表征,用 TG对聚合物的热稳定性进行了分析。
Aliphatic poly(styrene carbonate) was sytbesized by coordinate - catalytical copolymer- ization of carbon dioxide and styrene oxide(StO) with polymer - supported bimetallic catalysts (PBM) and was characterized with IR, 1 HNMR and DSC. The thermal degradation of copolymers was studied by TG and found that 5 % and 50% weight loss temperature (t5%, t50% ) were 218℃and 271 ℃ respectively.
出处
《广州化学》
CAS
2000年第4期1-4,共4页
Guangzhou Chemistry
基金
国家自然科学基金资助项目(29734120)