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二氧化碳-氧化苯乙烯的共聚反应 被引量:2

Copolymerization of Carbon Dioxide and Styrene Oxide by Polymer - Supported Bimetallic Catalysts
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摘要 由CO2-氧化苯乙烯(StO)配位催化共聚制得脂肪族聚碳酸苯亚乙酯,并用 IR、1HNMR和 DSC等进行表征,用 TG对聚合物的热稳定性进行了分析。 Aliphatic poly(styrene carbonate) was sytbesized by coordinate - catalytical copolymer- ization of carbon dioxide and styrene oxide(StO) with polymer - supported bimetallic catalysts (PBM) and was characterized with IR, 1 HNMR and DSC. The thermal degradation of copolymers was studied by TG and found that 5 % and 50% weight loss temperature (t5%, t50% ) were 218℃and 271 ℃ respectively.
出处 《广州化学》 CAS 2000年第4期1-4,共4页 Guangzhou Chemistry
基金 国家自然科学基金资助项目(29734120)
关键词 二氧化碳 氧化苯乙烯 共聚反应 玻璃化转变温度 热稳定性 聚碳酸苯亚乙酯 carbon dioxide, styrene oxide, copolymerization, glass transition temperature, ther- mostability
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