摘要
以水玻璃和Ti(SO4 ) 2 为原料 ,制备出了多孔的纳米TiO2 /SiO2 复合粒子。在后处理过程中 ,利用无机包覆剂溶解度随温度的变化 ,在复合粒子表面包覆了一层无机结晶膜。经热处理除去包覆剂后 ,得到了以单分散纳米复合粒子组成的复合微粉。对复合微粉进行比表面和孔容测试 ,并运用XRD和TEM进行了表征。发现TiO2 以 12 6nm的纳米晶粒的形式被多孔的SiO2 包覆 ,所形成的复合粒子则约为2 0nm。为了了解复合微粒的灭菌效果 ,运用纳米TiO2 和复合粉末对 4种保健食品进行对照灭菌实验。两个月以后 ,测得含复合微粒的样品中的菌落总数为 5 0～ 12 0个 / g ,是相应保健食品企业标准许可菌落数的 0 2 5 %～ 0 .7% ,为相应空白样和纳米TiO2 粉样品菌落数的 0 .5 2 %～ 0 .97%和33 .3%～ 83 .3 %
Porous nanometer TiO 2/SiO 2 composite particles are prepared by Ti(SO 4) 2 and water glass.During the process of washing and drying,inorganic surface modifier(NS-1) was employed to form inorganic film on nanometer composite particles,taking advantage of the solubility change with temperature of the inorganic modifier.Naturally,monodisperse composite powder was obtained after the decomposition of inorganic modifier by heat treatment.By means of specific surface area and pore volume,XRD and TEM,the characteristics of the composite particles were investigated.It was indicated that TiO 2 particles are coated with porous SiO 2 film in the form of 12.6nm crystal particles,and the sizes of composite particles are about 20nm.In order to learn the sterilization effect of the TiO 2/SiO 2 composite nanometer powder,nanometer TiO 2 and the composite powder were applied to several kind of health care foodstuffs.After two months,the total numbers of bacteria in the samples of composite powder were only 50 to 120 units per gram.Those were 0.25%～0.7% of the enterprise standards of those health care foodstuffs,and were 0.52%～0.97% of the bacteria numbers of blank samples and 33.3%～83.3% of those of samples containing pure nanometer TiO 2 powder.
出处
《中国粉体技术》
CAS
2001年第5期23-26,共4页
China Powder Science and Technology
基金
国家级科技成果重点推广计划项目 ( 980 10 2 11A)
江苏省科技发展基金项目 (BF2 0 0 0 0 10
