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空气气氛下木材表观热解动力学(英文) 被引量:8

Thermogravimetric Analysis on Global Mass Loss Kinetics of Leaf, Bark and Wood Pyrolysis in air Atmosphere
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摘要 研究了空气气氛下马尾松和楠木的树叶、树皮和树干试样的热解过程 ,发现每种试样的热解均包含两步主要的失重过程 ,在 6 0 0℃时总失重均达90 %以上。利用积分方法建立了适用于所有试样的两阶段一级动力学模型 。 The thermal decomposition of the leaf, bark and wood of masson pine (Pinus massoniana) and nanmao (Michelia macclurei) have been studied by using dynamic thermogravimetry under air atmospheric conditions. It is found that in all cases two main weight loss processes took place and the total weight loss at 600℃ was over 90%. By means of the integral method, the weight loss curves obtained for all cases are all best described by a two stage first order kinetic model, which is justified by the reconstruction of the thermal analysis data. The thermal stability of the leaf, bark, and wood for each material is estimated and discussed, and it is found that wood has the lowest thermostability.
出处 《火灾科学》 CSCD 2001年第3期125-134,共10页 Fire Safety Science
关键词 热解 木材 动力学 空气气氛 表观现象 thermogravimetry wood leaf bark thermostability decomposition kinetics
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参考文献5

  • 1Liu N A,Fire and Materials,1998年,22卷,103页
  • 2Huang M R,J Appl Polym Sci,1998年,68卷,293页
  • 3Wu Y,Thermochim Acta,1998年,324卷,49页
  • 4Chang W L,J Appl Polym Sci,1994年,53卷,1759页
  • 5Kung H C,Fifteenth Symposium(Int)On Combustion,1975年,243页

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