摘要
用流变相反应法合成了CuSal(Sal=o -OC6 H4 CO2 ) .用TG ,IR ,XRD和磁矩对其结构进行了表征 .X -射线粉末衍射结果表明配合物属于单斜晶系 ,其晶胞参数为 :a =15.3575(49) (10 - 10 m) ,b =15.96 36 (87) (10 - 10 m ) ,c =7.86 6 5(47) (10 - 10 m) ,β =94 .3,V =192 3.1(95) (10 - 10 m) 3,Z =12 ,Dcalc=2 .0 6 8g/cm3,Dexp=2 .0
Copper salicylate Cu( o -OC 6H 4CO 2) was synthesized by the rheological phase reaction method. The structure was characterized by IR , TG, X-ray power diffraction and magnetic moment. XRD indicated the complex is monoclinic crystal system and the crystal cell parameters are a=15.3575(49)(10\+ -10 m ),b=15.9636(87)(10\+ -10 m ),c=7.8665(47)(10\+ -10 m ),β=94.3,V=1923.1(95)(10\+ -10 m ) 3,Z=12,D calc =2.068 g/cm \+3,D exp =2.054 g/cm\+3.
基金
国家自然科学基金资助课题 (No .2 99710 2 4)
关键词
水杨酸铜
流变相反应
合成
表征
铜配合物
copper salicylate
rheological phase
synthesis
characterization
