摘要
The complex of iron（Ⅲ）hydroxide benzoate monohydrate,[Fe3（C6H5COO）7（OH）2]·H2O was synthesized with rheological phase reaction.The complex was characterized by elemental analysis and IR.The mechanism of thermal decomposition for iron（Ⅲ）hydroxide benzoate monohydrate in O2 and N2 was studied by using TG,DTG,DTA,IR and FABMS.The solid product of thermal decomposition of iron（Ⅲ）hydroxide benzoate monohydrate in O2 was Fe2O3.Iron（Ⅲ）hydroxide benzoate monohydrate in N2 decomposted to form Fe3O4 and organic compounds.The organic compounds obtained from decomposition reaction are mainly benzophenone,benzoate acid,triphenylmethane and so on.
The complex of iron（ Ⅲ ） hydroxide benzoate monohydrate, [ Fe3 （ C6 H5 COO） 7（OH） 2 ]·H2O was synthesized with theological phase reaction. The complex was characterized by demental analysis and IR. The mechanism of thermal decomposition for iron（ Ⅲ ）hydroxide benzoate monohydrate in O2 and N2 was studied by using TG, DTG, DTA, IR and FABMS. The solid product of thermal decomposition of iron（ Ⅲ） hydroxide benzoate monohydrate in O2 was Fe2O3. Iron（ Ⅲ ） hydroxide benzoate monohydrate in N2 deeomposted to form Fe3O4 and organic compouhds. The organic compounds obtained from decomposition reaction are mainly benzophenone, benzoate acid, triphenylmethane and so on.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2006年第2期195-198,共4页
Chemical Research and Application
基金
国家自然科学基金(20071026)资助项目
河南省科技厅星火科技攻关项目(0124020221)资助项目
关键词
一水合碱式苯甲酸铁(Ⅲ)
流变相反应
热分解
iron（ Ⅲ ）hydroxide benzoate monohydrate
theological phase reaction
thermal decompostition
