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层状液晶微环境对水杨酸铜配合物SOD样活性的影响

The Effect of Lamellar Liquid Crystals System on SOD like Activity of Copper Salicylate Complex
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摘要 Copper Salicylate complex was synthesized and its ability that inhibits the reduction of NBT by the superoxide radical(O ·- 2) was measured in aqueous solution and in AOT, TX 100, CTAB lamellar liquid crystals systems. It is obtained that the copper complex had SOD like activity either in solution(ID 50 =1.1×10 -6 mol/L) or in AOT lamellar liquid crystal(ID 50 =2.0×10 -5 mol/L). Experiments show that AOT lamellar liquid crystal had SOD like activity itself. The synergism of copper complex and AOT lamellar liquid crystal can enhance the SOD like activity of the system. Copper Salicylate complex was synthesized and its ability that inhibits the reduction of NBT by the superoxide radical(O ·- 2) was measured in aqueous solution and in AOT, TX 100, CTAB lamellar liquid crystals systems. It is obtained that the copper complex had SOD like activity either in solution(ID 50 =1.1×10 -6 mol/L) or in AOT lamellar liquid crystal(ID 50 =2.0×10 -5 mol/L). Experiments show that AOT lamellar liquid crystal had SOD like activity itself. The synergism of copper complex and AOT lamellar liquid crystal can enhance the SOD like activity of the system.
出处 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1999年第10期1520-1522,共3页 Chemical Journal of Chinese Universities
基金 国家自然科学重点基金 攀登计划子课题
关键词 水杨酸铜 层状液晶 配合物 SOD 模拟物 Lamellar liquid crystals, Cu(Ⅱ) complex, SOD like activity
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