摘要
The binuclear complex Sm2(C12H8N2)2(C6H5COO)6 has been prepared and structurally analyzed by single crystal Xray diffraction. The complex crystallizes in the triclinic system, space group P1 , with a=10.833(2), b=11.937(2), c=12.448(3) , = 104.97(3), = 93.63(3), = 113.27(3), V=1403.5 3, Dc=1.64g/cm3, =21.42cm-1, F(000)=690, Z=1, final R=0.037, Rw=0.077 for 4855 observed reflections I>2(I) and 5703 independent reflections. In the molecule, each Sm atom is coordinated by seven O atoms and two N atoms forming an irregular coordination polyhedron.
