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Template-directed Synthesis of Carboxylic Acid-functionalized Tetracationic Cyclophane 被引量:1

Template-directed Synthesis of Carboxylic Acid-functionalized Tetracationic Cyclophane
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摘要 Introduction Although devices based on pseudorotaxanes, cantenanes, and rotaxanes are commercialized yet, several researches have been done on the applications of these donor-acceptor molecules. A promising area is the field of nanotechnology. The miniaturization of semi-conductor technology by the "top-down" approach is limited by the wavelength of the radiation used in the lithography to prepare electronic components. Therefore, the "bottom-up" may be more suitable to create devices with sizes down to the molecular level. A molecular or supramolecular system, in which the relative position of the component parts can be altered by an external stimulus, a molecular switch, can act as the basic unit for the creation of new molecular devices . Introduction Although devices based on pseudorotaxanes, cantenanes, and rotaxanes are commercialized yet, several researches have been done on the applications of these donor-acceptor molecules. A promising area is the field of nanotechnology. The miniaturization of semi-conductor technology by the "top-down" approach is limited by the wavelength of the radiation used in the lithography to prepare electronic components. Therefore, the "bottom-up" may be more suitable to create devices with sizes down to the molecular level. A molecular or supramolecular system, in which the relative position of the component parts can be altered by an external stimulus, a molecular switch, can act as the basic unit for the creation of new molecular devices .
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2007年第6期745-748,共4页 高等学校化学研究(英文版)
基金 Supported by the National Natural Science Foundation of China(No.20272019).
关键词 Ethyl 3 5-bis(bromomethyt) benzoate Cyetophane TEMPLATE Synthesis Ethyl 3,5-bis(bromomethyt) benzoate Cyetophane Template Synthesis
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