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三聚磷腈的制备新工艺 被引量:9

Preparation of Phosphorus Nitride Dichloride Oligomers
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摘要 Hexachlorocyclotriphosphazene was prepared by reacting ammonium chloride and phosphorus pentachloride in an inert organic solvent at the presence of different metal compounds and pyridine. The conbination of MgCl2·6H2O with pyridine showed an ideal catalytic activity to give hexachlorocyclotriphosphazene in yield of 87% under the suitable conditions. The method is time saving. Hexachlorocyclotriphosphazene was prepared by reacting ammonium chloride and phosphorus pentachloride in an inert organic solvent at the presence of different metal compounds and pyridine. The conbination of MgCl_2·6H_2O with pyridine showed an ideal catalytic activity to give hexachlorocyclotriphosphazene in yield of 87% under the suitable conditions. The method is time saving.
出处 《应用化学》 CAS CSCD 北大核心 2001年第2期163-164,共2页 Chinese Journal of Applied Chemistry
基金 航空院校自选课题基金
关键词 三聚磷腈 氯化铵 五氯化磷 催化合成 hexachlorocyclotriphosphazene,ammonium chloride,phosphorus pentachloride,synthesis
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