期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice 被引量：1

Nitrosation Reaction Without Nitrogen Oxide Waste Gas Emission and Its Engineering Practice
在线阅读 下载PDF
导出
摘要 The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction.are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing＇the decomposition＇of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level.Thus the zero release ofnitrogen ox!de waste gas can be achieved without using any absorption process. The gas-liquid phase equilibrium is used in controlling the nitrosation reaction process. Decomposition of nitrous acid and oxidation side reaction are suppressed in a closed reaction system. The system pressure is used as the criterion of the end of reaction, avoiding excessive feeding and reducing the decomposition of nitrous acid. The head space of the reactor is used as the gas buffer, stabilizing the feeding fluctuations and inhibiting the side reaction, decomposition of nitrous acid. Nitrogen oxide concentration is controlled at the minimum level. Thus the zero release of nitrogen oxide waste gas can be achieved without using any absorption process.
作者 陈春光 冯亚青 牛伟玮 陈学玺
机构地区 School of Chemical Engineering and Technology Huangdao Entry-Exit Inspection and Quarantine Bureau School of Polymer Science and Engineering School of Chemical Engineering and Teclanology
出处 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2013年第4期442-446,共5页 中国化学工程学报（英文版）
关键词 nitrosa-tion nitrogen oxides phase equilibrium 亚硝化反应 废气排放量 氮氧化物 工程实践 亚硝酸 反应过程 平衡控制 反应体系
分类号 TQ03 [化学工程] O613.61 [理学—无机化学]
  • 相关文献

参考文献12

  • 1Williams, D.L.H., Nitrosation Reactions and the Chemistry of Nitric Oxide, Elsevier, Netherlands (2004).
  • 2Bolzan, R., “Peroxynitrite-mediated oxidations: Nitration and nitrosation”, Ph. D. Thesis, Louisiana State University, USA (2002).
  • 3Czepiel, P., Douglas, E., Harriss, R., Crill, P., “Measurements of N2O from composted organic wastes”, Environ. Sci. Technol, 30 (8), 2519-2525 (1996).
  • 4Barton, P.K., Atwater, J.W., “Nitrous oxide emissions and the anthropogenic nitrogen in wastewater and solid waste”, Journal of Environmental Engineering, 128 (2), 137-150 (2003).
  • 5Gong, Y.K., Wang, S.Y., Wang, S., Peng, Y.Z., “Nitrous oxide production from sequencing batch reactor sludge under nitrifying conditions: Effect of nitrite concentrations”, Environmental Technology, 33 (4), 401-408 (2012).
  • 6World Bank Group, “Nitrogen oxides: Pollution prevention and control”, In: Pollution Prevention and Abatement Handbook, World Bank Group, 245-249 (1998).
  • 7De Soete, G., “Nitrous oxide from combustion and industry: Chemistry, emissions, and control”, In: Proc. Int. IPCC Workshop on Methane and Nitrous Oxide: Methods in National Emissions Inventories and Options for Control, van Amstel, A.R., ed., The Netherlands, 287-337 (1993).
  • 8Braida, W., Ong, S.K., “Decomposition of nitrite under various pH and aeration conditions”, Water, Air, & Soil Pollution, 118 (1-2), 13-26 (2000).
  • 9Pires, M., Rossi, M.J., Ross, D.S., “Kinetic and mechanistic aspects of the NO oxidation by O2 in aqueous phase”, International Journal of Chemical Kinetics, 26 (12), 1207-1227(1994).
  • 10Steinitz, K., “A combined potassium iodide-starch reagent”, Microchimica Acta, 35 (2-3), 176-177 (1950).

同被引文献13

引证文献1

二级引证文献6

Chinese Journal of Chemical Engineering
2013年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部