摘要
苯直接羟基化合成苯酚是有机合成中具有挑战性的课题之一.本文总结了近十年来国内外各种反应体系,以H2O2、O2为绿色氧化剂,催化一步苯氧化羟基化反应,并对各方法进行了述评和展望.
The methodology of phenol synthesis via direct oxidation of benzene was one of the most challenging issues in organic synthesis.A variety of reaction systems both at home and abroad were summarized in recent decade,which used H 2 O 2 and O 2 as a green oxidant for one-step method of benzene oxidation hydroxylation.The methods were reviewed and the trend was prospected.
出处
《淮北师范大学学报(自然科学版)》
CAS
2012年第4期39-46,共8页
Journal of Huaibei Normal University:Natural Sciences
基金
安徽省自然科学基金项目(1208085MB32)
安徽省教育厅科研(重点)基金项目(KJ2011A250)
关键词
苯
绿色氧化
羟基化
进展
benzene
green oxidation
hydroxylation
progress