摘要
采用两种方法制备了三种Pt/CeO2-ZrO2-La2O3柴油车尾气氧化催化剂,并用X射线衍射、N2物理吸附、程序升温还原、程序升温脱附、X射线荧光光谱和红外光谱等方法对其进行了表征.结果发现,制备方法对催化剂的结构、织构、抗硫性能及催化性能的影响非常大.对其进行硫中毒,导致起燃温度明显升高.将ZrO2和La2O3沉积在CeO2表面所制得的Pt/CeO2-ZrO2-La2O3催化剂表现出更高的抗硫及催化氧化性能,这主要归功于Pt在富Zr载体表面具有更高的分散性.
Three Pt/CeO2-ZrO2-La2O3 diesel oxidation catalysts were prepared by two different routes and characterized by X-ray diffraction, N2 adsorption, temperature-programmed reduction, temperature-programmed desorption, X-ray photoelectron spectroscopy, and infrared spectroscopy. The synthesis procedure affected the structure, texture, sulfur resistance, and catalytic activity of the catalysts. Sulfur poisoning increased the light-off temperature of all the catalysts, but the Pt/CeO2-ZrO2-La2O3 catalyst prepared by depositing ZrO2 and La2O3 on the surface of CeO2 nanoparticles exhibited better sulfur tolerance and catalytic activity with simulated diesel emission due to the high dispersion of Pt on CeO2-ZrO2-La2O3 oxide with a Zr-rich surface.
出处
《催化学报》
SCIE
EI
CAS
CSCD
北大核心
2011年第9期1469-1476,共8页
基金
国家科技支撑计划(2007BAE08B01)~~
关键词
氧化铈
氧化锆
氧化镧
铂
沉积沉淀
硫中毒
柴油车尾气净化
ceria
zirconia
lanthana
platinum
deposition-precipitation
sulfur-poisoning
diesel exhaust purification
