期刊文献+

二茂铁对正庚烷池火抑制特性的实验研究 被引量:2

Study on suppression characteristic of Heptane fire and Ferrocene
在线阅读 下载PDF
导出
摘要 基于质量损失速率的热释放速率方法,通过改变二茂铁浓度和载气流速进行二茂铁灭火实验,借此研究二茂铁对正庚烷池火的抑制特性。实验结果表明:(1)增大二茂铁浓度,其抑制正庚烷池火的效果会有明显提高,但饱和二茂铁蒸气的灭火性能同其浓度并非成正比,而是存在一个最佳浓度;(2)在实验的N2流量范围内,增大载气N2的流量,二茂铁熄灭正庚烷火的效果也越好。实验中,N2的流量为0.75 m3/h时二茂铁的灭火性能最好。 The heat release rate was measured based on the theory of mass losing rate.Through changing the concentration of Ferrocene and the flux of N2 in the experiment,the suppression characteristic of Ferrocene and Heptane fire was studied.The results show that the suppressing effect of Ferrocene increased with the Ferrocene concentration growing.At the same time,the suppression effectiveness of Ferrocene is not proportional with the concentration.There is an optimal concentration.In the experimental flow range of N2,the suppressing effect of Ferrocene is better with the increasing flow of N2.When the flow of N2 is 0.75 m3 / h,the suppressing effect of Ferrocene is best.
出处 《消防科学与技术》 CAS 北大核心 2010年第9期752-754,共3页 Fire Science and Technology
关键词 二茂铁 正庚烷 热释放速率 Ferrocene Heptane fire heat release rate
  • 相关文献

参考文献8

  • 1MILLER D R,EVERS R L,Skinner G B.Effects of various inhibitors on hydrogen-air flame speeds[J].Combustion and Flame.1963,7(1):137-142.
  • 2Linteris G T,RUMMINGER M D.Flame Inhibition by Ferrocene,Alone and with CO2 and CF3H[C].Proceedings.Halon Options Technical Working Conference,Albuquerque.2000.
  • 3LINTERIS G T,RUMMINGER M D.Flame Inhibition by Ferrocene and Blends of Inert and Catalytic Agents[C].Twenty-eighth Symposium on Combustion.The Combustion Institute,Edinburgh.2000.
  • 4LINTERIS G T,RUMMINGER M D.Flame Inhibition by Ferrocene,Carbon Dioxide,and Trifluoromethane Blends:Synergistic and Antagonistic Effects[C].Chemical and Physical Processes in Combustion.Eastern States Section Meeting,The Combustion Institute,North Carolina State University,Raleigh.NC.1999.
  • 5Hirasawa Taro,Sung Chih-Jen,Yang Zhiwei,et al.Effect of ferrocene addition on sooting limits in laminar premixed ethylene-oxygen-argon flames[J].Combustion and Flame.2004,139(4):288-299.
  • 6程远平,陈亮,张孟君.火灾过程中火源热释放速率模型及其实验测试方法[J].火灾科学,2002,11(2):70-74. 被引量:108
  • 7Jacobs M H G,Ekeren P J Van,Kruif C G.The vapour pressure and enthalpy of sublimation of ferrocene[J].The Journal of Chemical Thermodynamics.1983,15(7):619-623.
  • 8许彬,张永明,方俊,马绥华,刘勇.正庚烷热释放速率测量与研究[J].消防科学与技术,2006,25(3):304-307. 被引量:27

二级参考文献19

  • 1张和平,王蔚,杨昀,徐亮.全尺寸墙角火实验中木工板表面火蔓延研究[J].燃烧科学与技术,2004,10(6):506-510. 被引量:10
  • 2[1]ISO/CD 13388-Fire Safety Engineering. Design Fire Scenar ios and Design Fires [DB/CD]. May 1997.
  • 3[2]Walter W. Jones, Glenn P. Fomey. NIST TN 1431, A Technical Reference for CFAST: An Engineering Tool for Estimating Fire and Smoke Transport [ R]. National Institute of Standards and Technology, Building and Fire Research Labo ratory, Gaithersburg, MD 20899, March 2000:17 ~ 77.
  • 4[3]U. Schneider. Ingenieurmethoden im Baulichen Brandschutz [M]. expert-Verlag, Renningen, 2001:151 ~ 187.
  • 5[4]DIN Deusches Institut fuer Normung e.V. Baulicher Brand schutz im Industriebau [ M ]. Berlin: Kommentar zu DIN 18230. Beuth Verlag GmbH, 1999:301 ~ 336.
  • 6[5]ISO/CD 13393 Fire Safety Engineering. Subsystem 4.Detection, Activation and Suppression [ DB/CD ]. May 1997.
  • 7[6]U. Schneider. Bewertung des Abbrandverhaltens yon Stoffen und Waren[M]. Beitrag in Ingenieurmaessige Verfahren im Brandschutz (5). Koeln: VdS Schadenverhuetung. 1998:1~ 32.
  • 8[7]R. John. Rauch- und Waermeabzug bei Braenden in grossen Raeumen [J]. vfdb-Zeitschrift Forschung, Technik und Man agement im Brandschutz, 1988, 38(1): 21 ~ 25.
  • 9[8]ISO 5660-1. Fire tests Reaction to fire Rate of heat re lease from building products [S], First edition (1993).
  • 10[9]ISO 9705. Fire tests Full-scale room test for surface prod ucts [S], First edition (1993).

共引文献133

同被引文献18

引证文献2

二级引证文献9

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部