摘要
研究了新显色剂苯并噻唑重氮氨基偶氮苯（ＢＴＤＡＢ）与Ａｇ（Ⅰ）的双波长光度法的显色反应．实验结果表明，在ＴｒｉｔｏｎＸ１００及三乙醇胺存在下，于ｐＨ值约为１０５的Ｎａ２Ｂ４Ｏ７－ＮａＯＨ缓冲溶液中，试剂与Ａｇ（Ⅰ）可形成络合比为２∶１的稳定的紫红色络合物．该络合物在５３５ｎｍ和４４０ｎｍ处分别存在最大吸收和最负吸收，显色反应的表观摩尔吸光系数可达８５３×１０４Ｌ·ｍｏｌ－１·ｃｍ－１，Ａｇ（Ⅰ）量在０～０．５２ｍｇ·Ｌ－１范围内符合比尔定律．
Benzothiazolyldiazoaminoazobenzene(BTDAB)is a new reagent.Its colour reaction with silver () was studied.At pH of 10.3010.70 and in the presence of triton X100 and triethanolamine silver forms a purplered complex with the reagent.The composition of the complex is MR=12.Under this condition the maximum absorption and the minimum absorption are located at 440 nm and 535 nm respectively.The apparent molor absorptivity is 8.5310\+4 L\5mol\+\{-1\}\5cm\+\{-1\},and Beers law is obeyed in the rang of 00.52 mg\5L\+\{-1\}.This method is employed to determine trace amounts of silver in fixing solution and developer solution with satisfactory results.
出处
《沈阳化工学院学报》
1999年第2期151-154,共4页
Journal of Shenyang Institute of Chemical Technolgy
关键词
苯并噻唑
重氮氨基偶氮苯
银
光度法
显色反应
benzothiazolyldiazoaminoazobenzene
silver
dualwavelength spectrophotometry
