摘要
对近年来胶束电动毛细管色谱法（ＭＥＣＣ）分析手性化合物方面的工作进行了评述，简述了ＭＥＣＣ分离手性化合物的原理，并探讨了几种ＭＥＣＣ手性分离体系的分离机理。
An overview on applications of micelle electrokinetic capillary chromatography(MECC) in chiral compounds analysis is presented. Ionic chiral surfactants such as bile salts, long alkyl chain surfactants and high molecular weight surfactants, which can migrate with electroosmosis and its electrophoretic mobility, and interact with the solutes, are employed as chiral selectors. Addition of electrically neutral chiral selectors such as cyclodextrins is also successful in MECC separation. Theory of MECC enantiomer separation is briefly described.
出处
《色谱》
CAS
CSCD
北大核心
1999年第1期26-29,共4页
Chinese Journal of Chromatography
关键词
胶束电动
毛细管色谱
手性分离
MECC
拆分
micelle electrokinetic capillary chromatography, chiral separation, surfactant
