期刊文献+
任意字段
题名或关键词
题名
关键词
文摘
作者
第一作者
机构
刊名
分类号
参考文献
作者简介
基金资助
栏目信息

固体酸Amberlyst-15催化合成芳香醛邻苯二甲酰腙化合物 被引量：1

Synthesis of aromatic aldehyde phthalylhydrazones by acid resin Amberlyst-15
在线阅读 下载PDF
导出
摘要 用廉价、非均相、可循环的Amberlyst-15酸性树脂作为催化剂,以水和甲醇为溶剂,芳香醛、N-氨基邻苯二甲酰亚胺和对甲苯亚磺酸钠缩合消除反应,制备了5种芳香醛邻苯二甲酰腙,产率均在80%以上,并通过1HNMR、IR、HRMS和元素分析测试。 Aromatic aldehyde,N-aminophthalimide and sodium arenesulfinate were subjected to condensation using the inexpensive,heterogeneous and recycled Amberlyst-15 as catalyst in a water-methanol mixture to manufacture aromatic aldehyde phthalylhydrazones.The product yield exceeded 80%,and the structure of target compounds were confirmed by 1HNMR and IR spectroscopy.
作者 万婧 秦慧敏 宋国伟 李振江
机构地区 南京工业大学生物与制药工程学院
出处 《化学试剂》 CAS CSCD 北大核心 2010年第4期308-310,共3页 Chemical Reagents
基金 教育部科学技术研究重点资助项目(208049)
关键词 酸性树脂 酰腙 氨基磺酸 芳香醛邻苯二甲酰腙 acid resin acylhydrazone sulfamic acid aromatic aldehyde phthalylhydrazones
分类号 O625 [理学—有机化学]
  • 相关文献

参考文献13

  • 1ROLLAS S,KUCUKGUZEL S G.Biological activities of hydrazone derivatives[J].Molecules,2007,12(8):1 910-1 939.
  • 2OZMEN U O,OLGUN G.Synthesis characterization and antibacterial activity of new sulfonyl hydrazone derivatives and their nickel(Ⅱ) complexes,spectrochim[J].Spectrochimic Acta,2008,70(3):641-645.
  • 3NAWAR N,HOSNY N M.Synthesis,spectral and antimicrobial activity studies of o-aminoacetophenone o-hydroxylbenzoyldydrazone complexes[J].Trans.Met.Chem.,2000,25(1):1-8.
  • 4LI Zhen-jiang,REN Xing-hua,WEI Ping,et al.A convenient preparation of aliphatic and aromatic N-sulfonylimines mediated by sulfamic acid in aqueous media[J].Green Chem.,2006,5(8):433-436.
  • 5任星华,李振江,万婧,李维思,孙颖杰.合成芳香醛邻苯二甲酰腙化合物的简便方法[J].精细化工,2007,24(7):710-713. 被引量：2
  • 6EDMONT D,WILLIAMS D M.A new and versatile synthesis of 5-substituted pyrrolo[2,3-d]pyrimidines[J].Tetrahedron Lett.,2000,41(44):8 581-8 585.
  • 7YADAV J S,SUBBA REDDY B V,VISHNUMURTHY P.Amberlyst-15 as a novel and recyclable solid acid for the coupling of aromatic aldehydes with homopropargyl alcohol[J].Tetrahedron Lett.,2005,46(8):1 311-1 313.
  • 8SINGH K,ARORA D,SINGH S.Dowex-promoted general synthesis of N,N'-disubstituted-4-aryl-3,4-dihydropyrimidinones using a solvent-free Biginelli condensation protocol[J].Tetrahedron Lett.,2006,47(25):4 205-4 207.
  • 9SABOU R,HOELDERICH W F,RAMPRASAD D,et al.Synthesis of 7-hydroxy-4-methylcoumarin via the Pechmann reaction with amberlyst ion-exchange resins as catalysts[J].J.Catal.,2005,232(1):34-37.
  • 10RODOIFO D B,ALICIA S C.An efficient synthesis of 3,4-dihydro-1H-2,3-benzothiazine 2,2-dioxides using amberlyst 15 and amberlyst xn 1010[J].Synth.Commun.,2002,32(23):3 675-3 680.

二级参考文献24

  • 1龙德清,汪焱钢,李德江,王锋尖.5,7-二甲基-1,2,4-三唑并[1,5-a]嘧啶-2-甲酰腙类化合物的合成与生物活性[J].有机化学,2005,25(11):1498-1502. 被引量：29
  • 2梁卓文,郭家仁,孟建新.对二甲氨基苯甲醛双缩二氨基硫脲双酰腙的合成、表征及与Zn^(2+)的荧光反应[J].光谱实验室,2006,23(3):551-553. 被引量：3
  • 3Buuhoi N P,Xuong N D,Nam N H,et al.Tuberculostatic hydrazides and their derivatives[J].J Chem Soc,1953,(3):1358-1364.
  • 4Elsayed L,Iskander M F.Coordination compounds of hydrazine derivatives with transition metals[J].J Inorg Nucl Chem,1971,33(2):435-443.
  • 5Yang Z Y,Yang R D,Yu K B.Synthesis and crystal structure of a barium complex with pyruvic acid isonocotinoy hydrazone[J].Polyhedron,1996,15(21):3749-3753.
  • 6Nawar N,Hosny N M.Synthesis,spectral and antimicrobial activity studies of o-aminoacetophenone o-hydroxylbenzoyldydrazone complexes[J].Trans Met Chem,2000,25(1):1-8.
  • 7Ainscough E W,Brodie A M,Dobbs A J,et al.Antitumour copper(Ⅱ) salicylaldehyde benzoyhydrazone(H2sb) complexes[J].Inorg Chim Acta,1998,267(1):27-38.
  • 8Katyal M,Dutt Y.Analytical applications of hydrazones[J].Talanta,1975,22(2):151-166.
  • 9Lal R A,Adhikari S,Pal A,et al.Synthesis and characterization of the homobimetallic[bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazonato]-bisdioxomolybdenum(Ⅵ) tetrahydrate complex and its reactivity towards proton and electron donor reagents[J].J Chem Res(S),1997,(4):122-123.
  • 10Pelagatti P,Bacchi A,Carcelli M,et al.Palladium(Ⅱ) complexes containing a P,N chelating ligand Part Ⅲ[J].J Organomet Chem,1999,583(1-2):94-105.

共引文献1

同被引文献14

引证文献1

化学试剂
2010年 第4期

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部