摘要
据报道,含硅碳双键的化合物已能制备,但它在通常条件下不稳定,易于发生加成、异构化反应,研究最多的两个异构化反应是:
The titled isomerization, H2SiCH2→HSiCH3, was studied at HF/3-21G level. The variations in thermodynamic functions and the rate constant for this reaction are calculated. Considering both the thermodynamic and kinetic factors, we think that this isomerization reaction is favourable at a higher temperature. This conclusion is agreed with the experimental result . There is no effect of methyl substitution.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1989年第10期1059-106,共1页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
硅乙烯
异构化反应
Abinitioi法
Isomerization of silene, Ab initio, Analysis of thermodynamic and kinetic factors.
