摘要
将自制的铜铬催化剂用于合成气制甲醇和甲酸甲酯的反应。采用搅拌釜式反应器在液相中进行。在低温低压条件下（３８３Ｋ，４．０ＭＰａ），平均反应速率达到５８．２ｇ／（Ｌ·ｈ），甲醇和甲酸甲酯的总选择性接近１００％。
A slurry phase concurrent synthesis of methanol and methyl formate occured over a mixed catalyst of sodium methanoxide and a home made Cu Cr O compound. The reactions were carried out under pretty mild conditions (383K, 4.0MPa).The space time yield of methanol and methyl formate is 58.2 g/L·h, and the total selectivity of methanol and methyl formate is approximately 100%. The optimum value of Cu/Cr atom ratio is 1. The novel catalyst is characterised by no induction period.
出处
《天然气化工—C1化学与化工》
CAS
CSCD
北大核心
1997年第3期14-18,共5页
Natural Gas Chemical Industry
