摘要
用微热量计对亚甲基蓝与溴酸根在水中的氧化还原反应进行了热动力学研究。根据在微量热计上测得的数据和算得该反应的热力学参数(活化焓、活化熵及活化自由能)、数率常数和动力学参数(活化能、指前因子及反应级数),对此反应的机理也作了探讨。
Thermokinetic characteristics of the redox reaction between methylene blue solution and potassium bromate solution was studied by micro-calorimetry. Based on the data obntained with the micro-calorimeter, 3 thermodynamic parameters （i. e. , the activation entmlpy, the activation entropy and the activation free energy）, the reaction-rate constant, and 3 kinetic parameters （i. e. , the activation energy, the pre-exponential factor and the reaction order） of the redox reaction were calculated. A discussion on the reaction mechanism was also given.
出处
《理化检验（化学分册）》
CAS
CSCD
北大核心
2008年第4期307-309,共3页
Physical Testing and Chemical Analysis(Part B:Chemical Analysis)
基金
宁夏医学院面上科研项目(2006203)
关键词
微量热法
亚甲基蓝
溴酸钾
热动力学
微量热计
Micro-calorimetry
Methylene blue
Potassium bromate
Thermokinetics
Micro-calorimeter
