摘要
提出了固相反射分光光度法，并以Ｎｉ（Ⅱ）丁二酮肟ＴｒｉｔｏｎＸ１００体系为例拟定了测镍的固相反射光度法。方法简便、快速、灵敏，检测限为０．０２９ｍｇ·Ｌ１，精密度好（测定２５μｇ镍１１次，ＲＳＤ＝１．１％）。
A new solid phase reflection spectrophotometric method for the determination of nickel is proposed.The nickel in steel samples is separated from the solutions as Ni(Ⅱ) dimethylglyoxime complex,and is collected on filter paper for reflection analysis.The detection limit is 0.029 mg·L 1 .The experimental results showed that solid phase reflection spectrophotometric method was simple,rapid and sensitive.The RSD for 11 runs is 1.1 %.
出处
《分析测试学报》
CAS
CSCD
1997年第3期10-12,共3页
Journal of Instrumental Analysis
基金
九五地质科技研究项目
关键词
固相反射
分光光度法
镍
Solid phase reflection spectrophotometry (SRS),Nickel.
