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乙酰丙酮缩邻氨基苯酚对铜的萃取性能及萃取光度法

EXTRACTIVE PROPERTIES AND SPECTROPHOTOMETRY OF ACETYIACETON O AMINOPHENOL TO COPPER(Ⅱ)
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摘要 乙酰丙酮缩邻氨基苯酚对铜的萃取性能及萃取光度法*唐丽素刘春元龙云飞周建军(湘潭师范学院化学系湖南湘潭411100)关键词乙酰丙酮缩邻氨基苯酚铜(Ⅱ)萃取分光光度法中图分类号O657.32对铜的萃取分离已做了大量的研究工作,并在湿法冶金工业获得了应用[... The extractive behavior and extractive spectrophotometry of a novel schiff base ligand H 2acac o ap in CHCl 3 solution to Copper(Ⅱ) were studied.The experimental findings showed that the extractant complexed divalent copper had a ratio 1∶1.Under the nertral or weaker acidic conditions trace copper in aqueous phase was selectively and quantitatively extracted to organic phase (CHCl 3).The λ and ε of the chloroform extract were measured at 400nm and 1.28×10 4,respectively.And Beer′s law was applicable in the rang of 0~3μg/ml for copper.The proposed method can be used in separating and directly determinating trace copper without anti extraction.
出处 《化学研究与应用》 CAS CSCD 1997年第2期165-167,共3页 Chemical Research and Application
基金 湖南省重点学科资助
关键词 苯酚 萃取分光光度法 乙酰丙酮缩氨基 acetylaceton o aminophenol,Copper,extractive spectrophotometry
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