摘要
报道了用自行组装的流动注射化学发光分析仪，对茜素紫－乳化剂ＯＰ－Ｈ２Ｏ２－Ｔｉ（ＩＶ）化学发光新体系进行了研究．考察了测定钛的最佳条件，测定Ｔｉ（ＩＶ）的线性响应浓度为０．５×１０－７～８．０×１０－６ｇ·ｍｌ－１，检测下限达５０ｎｇ·ｍｌ－１，对２μｇ·ｍｌ－１（ＩＶ）进行了１１次重复测定，其ＲＳＤ为２．１％，对２８种常见的阴阳离子进行了干扰实验，表明方法具有较好的选择性，用于水样中钛的分析，结果令人满意．
A new method is reported for the determination of trace amount of Ti(Ⅳ) with Alizarin Volet OP H 2O 2 Ti(Ⅳ) chemiluminescence system by FIA. The detection limit of the method is 50 ng·ml -1 for Ti(Ⅳ). If the range of Ti(Ⅳ) concentration for the working curves is 0 5×10 -7 ～8 0×10 -6 g·ml -1 ,the peak height is found to be linearly dependent on the concentration of Ti(Ⅳ). The relative standard deviation is less than 2 1%. The method has been applied to determining Ti(Ⅳ) in water with satisfactory results.
出处
《东北大学学报（自然科学版）》
EI
CAS
CSCD
北大核心
1997年第3期338-341,共4页
Journal of Northeastern University(Natural Science)
基金
冶金部科学基金
关键词
流动注射分析
化学发光
茜素紫
钛
乳化剂
rFIA
reversed Flow Injection Analysis (rFIA),chemiluminescence (CL),Alizarin Viloet,titanium.
