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Annealing behaviors of vacancy in varied neutron irradiated Czochralski silicon

Annealing behaviors of vacancy in varied neutron irradiated Czochralski silicon
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摘要 The difference of annealing behaviors of vacancy-oxygen complex (VO) in varied dose neutron irradiated Czochralski silicon: (S1 5×1017 n/cm3 and S2 1.07×1019 n/cm3) were studied. The results show that the VO is one of the main defects formed in neutron irradiated Czochralski silicon (CZ-Si). In this defect, oxygen atom shares a vacancy, it is bonded to two silicon neighbors. Annealed at 200 ℃, divacancies are trapped by interstitial oxygen(Oi) to form V2O (840 cm-1). With the decrease of the 829 cm-1 (VO) three infrared absorption bands at 825 cm-1 (V2O2), 834 cm-1 (V2O3) and 840 cm-1 (V2O) will rise after annealed at temperature range of 200-500 ℃. After annealed at 450-500 ℃ the main absorption bands in S1 sample are 834 cm-1, 825 cm-1 and 889 cm-1 (VO2), in S2 is 825 cm-1. Annealing of A-center in varied neutron irradiated CZ-Si is suggested to consist of two processes. The first is due to trapping of VO by Oi in low dose neutron irradiated CZ-Si (S1) and the second is due to capture the wandering vacancy by VO, etc, in high dose neutron irradiated CZ-Si (S2), the VO2 plays an important role in the annealing of A-center. With the increase of the irradiation dose, the annealing behavior of A-center is changed. The difference of annealing behaviors of vacancy-oxygen complex (VO) in varied dose neutron irradiated Czochralski silicon: (S1 5×10^17n/cm^3 and S2 1.07×10^19n/cm^3) were studied. The results show that the VO is one of the main defects formed in neutron irradiated Czochralski silicon (CZ-Si). In this defect, oxygen atom shares a vacancy, it is bonded to two silicon neighbors. Annealed at 200℃, divacancies are trapped by interstitial oxygen(Oi) to form V20 (840 cm^-1). With the decrease of the 829 cm^-1 (VO) three infrared absorption bands at 825 cm-l (V202), 834 cm^-1 (V203) and 840 cm^-1 (V20) will rise after annealed at temperature range of 200-500 ℃. After annealed at 450-500 ℃ the main absorption bands in S1 sample are 834 cm ^-1, 825 cm^-1 and 889 cm ^-1 (VO2), in S2 is 825 cm ^-1. Annealing of A-center in varied neutron irradiated CZ-Si is suggested to consist of two processes. The first is due to trapping of VO by Oi in low dose neutron irradiated CZ-Si (S 1) and the second is due to capture the wandering vacancy by VO, etc, in high dose neutron irradiated CZ-Si (S2), the VO2 plays an important role in the annealing of A-center. With the increase of the irradiation dose, the annealing behavior of A-center is changed.
出处 《中国有色金属学会会刊:英文版》 CSCD 2006年第B01期113-115,共3页 Transactions of Nonferrous Metals Society of China
基金 Project(50472034) supported by the National Natural Science Foundation of China Project(E2005000048) supported by the Natural Science Foundation of Hebei Province, China Project(20050080006) supported by the Specialized Research Fund for the Doctoral Program of Higher Education, China.
关键词 快中子辐照直拉硅 A心 FTIR 退火行为 空穴 Czochralski silicon neutron irradiation A-center, FTIR
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参考文献8

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