摘要
合成了新型起爆药高氯酸·四氨·双叠氮基合钴(Ⅲ)(DACP)。通过IR、^1HNMR等对DACP的结构进行了表征,测定了DACP的主要性能。结果表明:DACP的性能类似于高氯酸·四氨·双(5-硝基四唑)合钴(Ⅲ)(BNCP),而且其合成比BNCP简单,是一种性能优良的起爆药,可取代BNCP和Pb(N3)2应用在某些火工品中。
A new initiating explosive-tetraamminediazido cobalt( Ⅲ) perchlorate(DACP) was synthesized. Its structure was characterized by the IR,^1HNMR etc. And the main properties were measured by the various methods. The results show that DACP is an excellent primary explosive similar to tetraamminebis(5-nitrotetrazolato) cobalt ( Ⅲ) perchlorate (BNCP) in functions. Synthetic method of DACP is much simpler than that of BNCP. In some initiating devices, DACP may be a substitute for BNCP and Pb(N3)2.
出处
《含能材料》
EI
CAS
CSCD
2006年第3期161-164,共4页
Chinese Journal of Energetic Materials
基金
十五武器装备预先研究项目(预2001429)