摘要
2-甲氧基-3,5-二硝基-6-叠氮基吡嗪(MDNAP)是一种新型含能化合物的母体,以2,6-二氯吡嗪为原料,经过甲氧基化合成得到2-甲氧基-6-氯吡嗪(MCP),得率81%.用硝硫混酸硝化MCP,在较温和的条件下得到2-甲氧基-3,5-二硝基-6-氯吡嗪(MDNCP),得率75%.MDNCP经叠氮化合成得到MDNAP,得率60%,各中间体均用IR、H1NMR、ESI-MS和EI-MS进行表征。
MDNAP is a precursor for novel energetic compounds.2-methoxy-6-chlorin pyrazine（MCP） was first synthesized from raw material 2,6-dichlorin pyrazine by substituting chlorine with methoxyl with a yield of 81%.2-methoxy-3,5-dinitryl-6-chlorin pyrazine（MDNCP） was obtained by the nitration of MCP with mixed nitric and sulfuric acids under facile conditions with a yield of 75%.2-methoxy-3,5-dinitryl-6-azide pyrazine（MDNAP） was synthesized from MDNCP by the zaide substitution of MDNCP with a yield of 60%.Therein,all the intermediates were characterized by IR,H1 NMR,ESI-MS and EI-MS.
出处
《兵工学报》
EI
CAS
CSCD
北大核心
2010年第10期1357-1362,共6页
Acta Armamentarii
