摘要
合成了稀土硝酸盐与双希夫碱邻香兰素缩邻苯二胺（以Ｌ表示）的３种新固体配合物。通过元素分析、红外光谱、紫外光谱、差热一热重、摩尔电导及Ｘ射线粉末衍射分析等手段，确定配合物的组成为（ＬｎＬ（ＮＯ３）２）ＮＯ３（Ｌｎ＝Ｎｄ、Ｓｍ、Ｅｕ）。并对其结构和某些物理化学性质进行了研究。
Three new solid complexes of lanthanide nitrates with bis-schiff base (L) derived from 0-vamillin and 0-phenylenediamine have been synthesized and characterized by elemental analysis, DTA-TG,IR, UV, mloar conductance and x-ray diffraction analysis. The compositions of the complexes were found to be [LnL (NO_3)_2]NO_3(Ln = Nd, Sm, Eu). The possible structures and some properties of the complexes were studied.
出处
《稀土》
EI
CAS
CSCD
1996年第4期1-4,共4页
Chinese Rare Earths
