摘要
本文报道了首次合成出的LnL型稀土钨镓三元杂多化合物K_6〔H_2OY_bGaW_(11)O_(39)〕·10H_2O和稀土钨铝三元杂多化合物K_6〔H_2OErAlW_(11)O_(39)〕·11H_2O,通过组成分析、磁性质测试,确定了其分子组成,并对其红外光谱、紫外光谱、热性质等进行了测试和初步研究。
New heteropoly Compounds K6[YbGaW11O40H2]·10H2O and K6[ErAlW11O40H2]·11H2O Were Propared for the first time.The Synthetic method of the Compounds, 1R and UV spectra, magnitic susleptibility and thermal behavior were investigated.
关键词
稀土-钨-镓
杂多酸盐
LnL型
rare earths, heteropoly complexes of tungsten and gallium elements, heteropoly complexes of tungsten and aluminium.
