摘要
以莰烯为原料，先经Ｖｉｌｓｍｅｉｅｒ－Ｈａａｃｋ甲酸化反应制得Ｅ型莰烯醛，将后者控制氧化得Ｅ型８－莰烯基甲酸（２）．在硫酸催化下使２分别与甲醇、乙醇、正丙醇、异丙醇进行酯化反应合成了２的，四种酯，并进行了纯化和结构分析．氧化及酯化的得率都较高，而且甲酯与乙酯的香气良好．
Four alkyl E-8-camphenylcarboxylic acid esters were synthesized by the esterifica tion of,E-8-camphenylcarhoxylic acid(2),Which,was.prapalred from comphene through Vilsmeier-Haack formylation and selected oxidation.All porducts.have been purified and analyzed. Both the esterification and oxidation had good yields,also methyl and ethyl E-8-cam phenylcarboxylic acid esters were a kind of favorable perfume,so it established a new way for the deep utilization of camphene.
出处
《江西师范大学学报（自然科学版）》
CAS
1996年第1期23-26,共4页
Journal of Jiangxi Normal University(Natural Science Edition)
基金
江西省自然科学基金
