摘要
本文在恒温固定床吸附柱中，分别装填不同型号、粒径的大孔磺酸树脂（吸附剂），在氮气、Ｃ４（气相）、Ｃ４（液相）三种不同的介质中，对甲醇的动态吸附特性进行考察．采用色谱扰动－应答技术，对得到的吸附柱脉冲应答曲线，按矩量分析法进行处理，取得了与工业操作相类似的条件下，甲醇在上述各种情况下的吸附平衡常数和吸附速度常数．结果表明该类树脂（吸附剂）。
The pulse response curve of adsorbate MeOH in various fluid phase (N 2、 C 4fraction in gas phase and C 4fraction in liquid phase) on resin sulphonated with a fixed bed is determined. The adsorption equilibrium constant K a and adsorption rate constant k a for these adsorption systems at 25℃ are obtained by the method of moments. The dynamic adsorption characteristic of the resin sulphonated for the MeOH in N 2and C 4fraction (gas phase) are about the same, and the experimental results show that adsorption of resin sulphonated for the MeOH in C 4liquid fluid is easily more than C 4gas fluid.
出处
《四川师范大学学报（自然科学版）》
CAS
CSCD
1996年第3期67-75,共9页
Journal of Sichuan Normal University（Natural Science）
关键词
大孔磺酸树脂
甲醇
吸附平衡常数
吸附剂
The resin sulphonated, Methanol, The pulse response technique, Adsorption equilibrium constant, Adsorption rate constant, C 4 hydrocarbon.
