摘要
2-(3,4,5-三甲氧基)苯基-4,9-二氢环庚并吡喃-4,9-二酮的一步合成高文涛(锦州师范学院化学系锦州121003)关键词缩杂环酮化合物,3,4,5-三甲氧基,苯甲醛,成环缩合,合成自然界中某些抗菌素和毒菌的基本组成中含有酮结构单元,具有抗癌...
A mixture of 3-acetyltropolone(1)and TMB(2)in ethyl orthoformate was refluxed for 10minutes in the presence of 70% perchloric to give 2-(3,4,5-trimethoxy) pheny1-4,9-dihydrocyclohepta[b]pyran-4,9-dione(3).3 is a new cumpound and its structure has been confirmeuby the IR、 ̄1H-NMR spectura analysis and elementary analysls。
出处
《化学研究与应用》
CAS
CSCD
1995年第4期404-405,共2页
Chemical Research and Application