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部分N-酰化脱乙酰壳多糖的水溶性 被引量:4

ON THE WATER SOLUBILITY OF PARTLY N-ACYLATED CHITOSANS
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摘要 甲壳素由于氢键缔结使其溶解度太小,而限制了应用.在甲壳素分子上引入大的酰基可改善其在有机溶剂中的溶解性.用冷冻强碱处理的方法也可制得水溶性甲壳素,但此法会引起甲壳素的降解.本文报导脱乙酰壳多糖的一些N-酰化衍生物,探讨它们的水溶性与N-酰化度等的关系. A series of partly N-acylated chitosans was prepared and their solubility and watersorption were studied. It was found that N-acetyl, N-propionylchitosan (degree of acylation55%), N-butyrylchitosan (degree of acylation 50%) dissolve fairly in water. The X-raydiffraction intensity curve of the water-soluble N-acetylchitosan showed that it was almostamorphous.
出处 《应用化学》 CAS CSCD 北大核心 1989年第3期90-92,共3页 Chinese Journal of Applied Chemistry
关键词 脱乙酰壳多糖 N-酰化 水溶性 Chitosan N--Acylation Water solubility
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