摘要
高分子镍催化剂催化甲醇羰基化制备乙酸潘平来，柳忠阳，黄茂开，袁国卿（中国科学院化学研究所北京１０００８０）关键词高分子镍催化剂，羰基化醇类的谈基化反应早在５０年代初就开始研究，ＲｅＰＰｌｅ［Ｕ等人研究发现周期表中第八族金属元素的藏基化物对甲醇谈基化有...
nickel complex of linear 2-vinylpyridine-Methyl Acrylate copolymers has been found to be able to catalyze the carbonylation of methanol to produce acetic acid in a mild conditions. Experimental results show that the polymer-nickel complex contains two kinds of coordination bonds, N→Ni and O→Ni.Catalytic activity of the complex is increasing with the augmentation of O→Ni bond.And it also shows that the complex has a resistant effect on poisoning of suphur compounds.
出处
《高分子学报》
SCIE
EI
CAS
CSCD
北大核心
1995年第5期632-635,共4页
Acta Polymerica Sinica
基金
国家自然科学基金
关键词
镍催化剂
羰基化
甲醇
乙酸
Polymer-Nickel catalyst,Carbonylation
