The radon control mechanism of Na_(2)O·nSiO_(2)−CaCl_(2)modified soil was studied through the laboratory simulation experiment of tailing covering radon control.The radon exhalation rate(J)is negatively correlate...The radon control mechanism of Na_(2)O·nSiO_(2)−CaCl_(2)modified soil was studied through the laboratory simulation experiment of tailing covering radon control.The radon exhalation rate(J)is negatively correlated with the coverage thickness(H),and it has a non-linear relationship with the temperature.The moisture content variation rate of the covering soil significantly decreases,which helps to reduce soil damage and enhance the resistance of the covering soil to ambient temperature interference.The formation of silicic gel and C−S−H gel effectively optimizes the pore structure and permeability,reduces the diffusion and migration of radon gas in the covering soil,and the average radon exhalation rate is decreased by 1.01×10^(−2)Bq/(m^(3)·s).The research results show that the Na_(2)O·nSiO_(2)−CaCl_(2)modified covering soil can effectively improve the radon control performance of the covering soil and reduce the cost of cover treatment.展开更多
The assay of trace volatile low molecular weight(MW) compounds in human breath or in ambient atmosphere typically involves gas chromatography with flame ionization detection (FID). This paper introduced a direct assa...The assay of trace volatile low molecular weight(MW) compounds in human breath or in ambient atmosphere typically involves gas chromatography with flame ionization detection (FID). This paper introduced a direct assay which can overcome the difficulties of collection low concentration samples. In order to pre concentrate the trace low MW compounds, a small trapping column filled with absorbent must be used before thermal desorption of the collected samples onto chromatographic column(packed with Porapak Q) for separation. It has been proved that the characteristic of absorbent mainly influence the recoveries and the linear range of this method is from 0 05 ng to 5200 ng for pentane, methanol, ethanol and acetone.展开更多
Radongas concentrations in soil samples were determined from depths (surface, 15, and 30) cm for nine locations in Al-Dora refinery and surrounding area using “sealed can technique” and CR-39 solid state nuclear tra...Radongas concentrations in soil samples were determined from depths (surface, 15, and 30) cm for nine locations in Al-Dora refinery and surrounding area using “sealed can technique” and CR-39 solid state nuclear track detectors. The radon concentration in surface samples ranged from 810.08 to 1380.08 Bq/m3 with an average 1137.71 Bq/m3. The radon concentration in soil at the depth 15 cm was ranged from 490.5 to 1197.52 Bq/m3 with an average 732.78 Bq/m3 and at the depth 30 cm was ranged from 362.07 to 889.53 Bq/m3 with an average 529.41 Bq/m3. The surface exhalation rate in surface soil samples ranged was 0.44, to 0.99 Bq·m-2·h-1 with average 0.61 Bq·m-2·h-1. The surface exhalation rate in soil samples at the depth 15 cm was ranged from 0.22 to 0.64 Bq·m-2·h-1 with average 0.39 Bq·m-2·h-1. The surface exhalation rate in soil samples at the depth 15 cm was ranged from 0.22 to 0.64 Bq·m-2·h-1 with average 0.39 Bq·m-2·h-1. The surface exhalation rate and the mass exhalation rate in soil samples at the depth 30 cm ranged from 0.19, to 0.48 Bq·m-2·h-1 with average 0.28 Bq·m-2·h-1. The mass exhalation rate in surface soil samples ranged from 0.09 to 0.21 Bq·kg-1·h-1 with average 0.12 Bq·kg-1·h-1. The mass exhalation rate in soil samples from depth 15 cm was ranged from 0.046 to 0.14 Bq·kg-1·h-1 with average 0.08 Bq·kg-1·h-1. The mass exhalation rate in soil samples at the depth 30 cm was ranged from 0.042 to 0.1 Bq·kg-1·h-1 with average 0.06 Bq·kg-1·h-1.展开更多
基金supported by the National Natural Science Foundation of China(No.51174116)the National Key Research and Development Program of China(No.2023YFC3010903)the Scientific Research Project of Education Department of Hunan Province,China(No.24A0319).
文摘The radon control mechanism of Na_(2)O·nSiO_(2)−CaCl_(2)modified soil was studied through the laboratory simulation experiment of tailing covering radon control.The radon exhalation rate(J)is negatively correlated with the coverage thickness(H),and it has a non-linear relationship with the temperature.The moisture content variation rate of the covering soil significantly decreases,which helps to reduce soil damage and enhance the resistance of the covering soil to ambient temperature interference.The formation of silicic gel and C−S−H gel effectively optimizes the pore structure and permeability,reduces the diffusion and migration of radon gas in the covering soil,and the average radon exhalation rate is decreased by 1.01×10^(−2)Bq/(m^(3)·s).The research results show that the Na_(2)O·nSiO_(2)−CaCl_(2)modified covering soil can effectively improve the radon control performance of the covering soil and reduce the cost of cover treatment.
文摘The assay of trace volatile low molecular weight(MW) compounds in human breath or in ambient atmosphere typically involves gas chromatography with flame ionization detection (FID). This paper introduced a direct assay which can overcome the difficulties of collection low concentration samples. In order to pre concentrate the trace low MW compounds, a small trapping column filled with absorbent must be used before thermal desorption of the collected samples onto chromatographic column(packed with Porapak Q) for separation. It has been proved that the characteristic of absorbent mainly influence the recoveries and the linear range of this method is from 0 05 ng to 5200 ng for pentane, methanol, ethanol and acetone.
文摘Radongas concentrations in soil samples were determined from depths (surface, 15, and 30) cm for nine locations in Al-Dora refinery and surrounding area using “sealed can technique” and CR-39 solid state nuclear track detectors. The radon concentration in surface samples ranged from 810.08 to 1380.08 Bq/m3 with an average 1137.71 Bq/m3. The radon concentration in soil at the depth 15 cm was ranged from 490.5 to 1197.52 Bq/m3 with an average 732.78 Bq/m3 and at the depth 30 cm was ranged from 362.07 to 889.53 Bq/m3 with an average 529.41 Bq/m3. The surface exhalation rate in surface soil samples ranged was 0.44, to 0.99 Bq·m-2·h-1 with average 0.61 Bq·m-2·h-1. The surface exhalation rate in soil samples at the depth 15 cm was ranged from 0.22 to 0.64 Bq·m-2·h-1 with average 0.39 Bq·m-2·h-1. The surface exhalation rate in soil samples at the depth 15 cm was ranged from 0.22 to 0.64 Bq·m-2·h-1 with average 0.39 Bq·m-2·h-1. The surface exhalation rate and the mass exhalation rate in soil samples at the depth 30 cm ranged from 0.19, to 0.48 Bq·m-2·h-1 with average 0.28 Bq·m-2·h-1. The mass exhalation rate in surface soil samples ranged from 0.09 to 0.21 Bq·kg-1·h-1 with average 0.12 Bq·kg-1·h-1. The mass exhalation rate in soil samples from depth 15 cm was ranged from 0.046 to 0.14 Bq·kg-1·h-1 with average 0.08 Bq·kg-1·h-1. The mass exhalation rate in soil samples at the depth 30 cm was ranged from 0.042 to 0.1 Bq·kg-1·h-1 with average 0.06 Bq·kg-1·h-1.
