We report a theoretical investigation into superconductivity within the MAXH_(6) quaternary hydride system using first-principles calculations,where M and A denote alkali and alkaline earth elements,respectively,and X...We report a theoretical investigation into superconductivity within the MAXH_(6) quaternary hydride system using first-principles calculations,where M and A denote alkali and alkaline earth elements,respectively,and X represents transition metal elements.Systematic analysis of electronic band structures,phonon dispersions,and electron-phonon coupling reveals that substitution of MA binary metal combinations and X metal atoms can create favorable conditions for superconductivity.Mapping of superconducting critical temperatures,combined with dynamical stability analysis through phonon calculations,identifies ten superconducting candidates at ambient pressure.Among these,LiNaAgH_(6) exhibits nearly-free-electron behavior reminiscent of monovalent electron superconductors.It demonstrates exceptional superconducting properties with electron–phonon coupling λ=2.707,which yields a superconducting transition temperature T_(c) of 206.4 K using the Allen–Dynes formula.Its structural analogs MgNaPdH_(6),LiMgPdH_(6),LiMgAgH_(6),LiMgAuH_(6) all exhibit superconducting transition temperatures above 110 K.These findings advance our fundamental understanding of superconductivity in quaternary hydrides and provide guidance for rational design of new high-temperature superconducting materials.展开更多
A series of multi-hydroxyl bis-(quaternary ammonium)ionic liquids(Ils1‒7)was prepared as bifunctional catalysts for the chemical fixation of CO_(2).All these ionic liquid compounds were efficient for the catalytic syn...A series of multi-hydroxyl bis-(quaternary ammonium)ionic liquids(Ils1‒7)was prepared as bifunctional catalysts for the chemical fixation of CO_(2).All these ionic liquid compounds were efficient for the catalytic synthesis of cyclic carbonates and oxazolidinones via the cycloaddition reactions between CO_(2) and epoxides or aziridines with excellent yield and high selectivity in the absence of co-catalyst,metal and solvent.Due to the synergistic effects of hydroxyl groups and halogen anion,the cycloaddition reactions proceeded smoothly either at atmospheric pressure or room temperature.The selectivity for substituted oxazolidinones at 5-and 4-positions can be tuned via changing the reaction conditions.Finally,possible mechanisms including the activation of both CO_(2) and epoxide or aziridines were proposed based on the literatures and experimental results.展开更多
The organic pollutants,such as quaternary ammonium compounds,in high salinity flowback water from shale gas extraction may pose a severe risk to public health.Conventional biological technologies have limited effectiv...The organic pollutants,such as quaternary ammonium compounds,in high salinity flowback water from shale gas extraction may pose a severe risk to public health.Conventional biological technologies have limited effectiveness in the treatment of high-salt wastewaters,whereas electrocatalytic oxidation has shown potential for treating organic pollutants in high-salt flowback water.This study developed a carbon nanotubes(CNTs)doped Ru/Ir oxide coated Ti electrode CNTs-(Ru_(x)Ir_(y)O_(2))/Ti,which exhibited enhanced electrocatalytic performance for the treatment of quaternary ammonium compound in high-salt wastewater compared to the control metal oxide coated Ti anode(Ru_(x)Ir_(y)O_(2))/Ti,with pseudofirst-order reaction rate constant improved from 7.36×10^(-3) to 1.12×10^(-2) min−1.Moreover,the CNTs-(Ru_(x)Ir_(y)O_(2))/Ti anode electrocatalytic oxidation system exhibited excellent cycling stability.Mechanism studies indicated that the CNTs-(Ru_(x)Ir_(y)O_(2))/Ti electrode enhanced singlet oxygen(^(1)O_(2))generation,which played a major role in pollutant degradation.Furthermore,the formation of high concentrations of HClO and H_(2)O_(2) further facilitated the generation of ^(1)O_(2).This study may provide an efficient and green technology for the treatment of organic pollutants in high-salt shale gas flowback water.展开更多
Micro-arc oxidation(MAO)flm can only provide common mechanical protection for magnesium(Mg)–lithium(Li)alloys.These alloys are susceptible to severe localized corrosion,if the MAO flm is disrupted.This work reports t...Micro-arc oxidation(MAO)flm can only provide common mechanical protection for magnesium(Mg)–lithium(Li)alloys.These alloys are susceptible to severe localized corrosion,if the MAO flm is disrupted.This work reports the successful hydrothermal preparation of a MgLiAlCe-LDHs@GO flm on a MAO-coated Mg–Li alloy following Ce confnement.The graphene oxide(GO)sheet increased the difusion path of the corrosive media,and the addition of rare-earth cerium ions(Ce^(3+))endowed the flm with a certain self-healing ability,which signifcantly improved the corrosion resistance of the flm,and the corrosion current density(icorr)reached 3.27×10^(−8)A cm^(−2).The synergistic action of GO and Ce^(3+)can achieve long-term corrosion protection for the substrate.The corrosion resistance mechanism of MgLiAlCe-LDHs@GO flm was discussed by the scanning vibration electrode technique(SVET).展开更多
Although the late Quaternary slip rate of the Northern Margin Fault of the Huaizhuo Basin(NFHB)was studied approximately 30 years ago using thermoluminescence and geomorphic methods,the underlying uncertainty cannot b...Although the late Quaternary slip rate of the Northern Margin Fault of the Huaizhuo Basin(NFHB)was studied approximately 30 years ago using thermoluminescence and geomorphic methods,the underlying uncertainty cannot be neglected,considering the limitations resulting from age and displacement measurements.Accordingly,we attempted to re-estimate the late Quaternary slip rate of the NFHB using high-precision remote sensing image interpretation,large-scale geological and geomorphic mapping,paleoseismic analysis,and Quaternary geochronology testing.The results,based on stratigraphic dislocation and age constraint in the trenches,show that the present deformation of the NFHB has been dominated by the extension,with a vertical slip rate~0.04-0.11 mm/a.We estimate a vertical slip rate of~0.06 mm/a,with an R^(2) value of~0.91,which is much lower than the~0.5 mm/a result estimated previously.There are three possible reasons for this discrepancy.The first is the limitation resulting from dating and displacement measurements in earlier studies;the second is the slip decomposition caused by multiple branches of the NFHB,which leads to the low slip rate observed at a single fault;and third possible explanation is that the fault may be locked at present with a low slip rate,which means that the earthquake hazard of the NFHB cannot be ignored,and more in-depth research,such as geodetic and intensive observations of earthquake precursors,is urgently needed.This discovery poses a new challenge for the active study of the NFHB and the northeast corner of the Ordos Plateau in the North China Block.展开更多
Ocean Drilling Program (ODP) Site 807A was recovered from the Ontong-Java plateau, western equatorial Pacific. Quantitative analysis of planktonic foraminifera, combined with oxygen and carbon isotope data, reveals th...Ocean Drilling Program (ODP) Site 807A was recovered from the Ontong-Java plateau, western equatorial Pacific. Quantitative analysis of planktonic foraminifera, combined with oxygen and carbon isotope data, reveals the glacial-interglacial variations of sea-surface temperature and the upper water vertical structure in this region during the late Quaternary. Our results indicate that since 530 ka sea-surface temperature (SST) and the depth of thermocline (DOT) have changed significantly in the western Pacific warm pool (WPWP). The average glacial-interglacial annual SST difference was up to 4.2 ℃, and the DOT fluctuations could exceed more than 100 m, further suggesting the instability of the WPWP. The spectral analyses of SST and DOT reveal two dominating cyclicities—the typical 100 ka cycle and the semi-precessional cycle, which is significant in the tropical spectrum, indicating that late Quaternary paleoceanographic changes in the study area were influenced not only by a high latitude forcing but also by tropic-driving factors.展开更多
Debris flows have increased in frequency within the arid Daheba Basin on the northeastern Tibetan Plateau,but their sediment sources remain poorly quantified.Using high-resolution UAV-derived DEMs from 51 small catchm...Debris flows have increased in frequency within the arid Daheba Basin on the northeastern Tibetan Plateau,but their sediment sources remain poorly quantified.Using high-resolution UAV-derived DEMs from 51 small catchments,this study evaluates the relative contributions of landslide-derived and channel-derived sediment in controlling debris-flow fan magnitude,and quantifies sediment supply during the 2023 rainy season using DEM differencing.A total of 766 landslides occurred predominantly on slopes of 40°-50°and southeast-southwest aspects,generating 36.17×10^(4)m^(3)of material.Gully heads exhibit exceptionally lower landscape dissection thresholds compared with loess and Quaternary regions in China,indicating high susceptibility to failure under intensified runoff.The results show that Landslide area-volume scaling exponent(b)varies with hillslope geometry(K_(u)):b>1.3 for K_(u)<8 and generally b<1.3 for K_(u)>8,indicating more complete scar evacuation upslope and partial erosion downslope.Despite the abundance of landslides,their contribution to debris flow fan magnitude is minor(<25%),with channel debris dominating(>75%).DEM differencing of a small catchment before and after the 2023 rainy season further reveals that sediment supply originates primarily from the main channel(60.6%)and tributaries(23.3%),with smaller contributions from channel banks(6.8%)and channel heads(9.2%).Tributaries exhibit the greatest mean erosion depth(4.2 m),exceeding that of the main channel(3.8 m).These findings demonstrate that debris-flow material supply in the Daheba Basin is transport-limited and controlled mainly by fluvial entrainment rather than slope failures.Climatic warming and wetting may enhance slope instability,but sediment mobilization is dominantly governed by runoff-driven channel erosion.This study underscores the importance of prioritizing channel sediment dynamics in debris flow hazards assessments for arid regions of the Tibetan plateau.展开更多
基金supported by the National Key R&D Program of China (Grant No.2022YFA1403201)the National Natural Science Foundation of China (Grant Nos.12125404,T2495231,123B2049,and 12204138)+9 种基金the Advanced MaterialsNational Science and Technology Major Project (Grant No.2024ZD0607000)the Natural Science Foundation of Jiangsu Province (Grant Nos.BK20233001 and BK20253009)the Jiangsu Funding Program for Excellent Postdoctoral Talent (Grant No.2024ZB002)the China Postdoctoral Science Foundation (Grant No.2025M773331)the Fundamental and Interdisciplinary Disciplines Breakthrough Plan of the Ministry of Education of Chinathe AI&AI for Science program of Nanjing UniversityArtificial Intelligence and Quantum physics (AIQ) program of Nanjing Universitythe Fundamental Research Funds for the Central Universitiesthe Natural Science Foundation of Nanjing University of Posts and Telecommunications(Grant Nos.NY224165,NY220038,and NY219087)the Hua Li Talents Program of Nanjing University of Posts and Telecommunications。
文摘We report a theoretical investigation into superconductivity within the MAXH_(6) quaternary hydride system using first-principles calculations,where M and A denote alkali and alkaline earth elements,respectively,and X represents transition metal elements.Systematic analysis of electronic band structures,phonon dispersions,and electron-phonon coupling reveals that substitution of MA binary metal combinations and X metal atoms can create favorable conditions for superconductivity.Mapping of superconducting critical temperatures,combined with dynamical stability analysis through phonon calculations,identifies ten superconducting candidates at ambient pressure.Among these,LiNaAgH_(6) exhibits nearly-free-electron behavior reminiscent of monovalent electron superconductors.It demonstrates exceptional superconducting properties with electron–phonon coupling λ=2.707,which yields a superconducting transition temperature T_(c) of 206.4 K using the Allen–Dynes formula.Its structural analogs MgNaPdH_(6),LiMgPdH_(6),LiMgAgH_(6),LiMgAuH_(6) all exhibit superconducting transition temperatures above 110 K.These findings advance our fundamental understanding of superconductivity in quaternary hydrides and provide guidance for rational design of new high-temperature superconducting materials.
文摘A series of multi-hydroxyl bis-(quaternary ammonium)ionic liquids(Ils1‒7)was prepared as bifunctional catalysts for the chemical fixation of CO_(2).All these ionic liquid compounds were efficient for the catalytic synthesis of cyclic carbonates and oxazolidinones via the cycloaddition reactions between CO_(2) and epoxides or aziridines with excellent yield and high selectivity in the absence of co-catalyst,metal and solvent.Due to the synergistic effects of hydroxyl groups and halogen anion,the cycloaddition reactions proceeded smoothly either at atmospheric pressure or room temperature.The selectivity for substituted oxazolidinones at 5-and 4-positions can be tuned via changing the reaction conditions.Finally,possible mechanisms including the activation of both CO_(2) and epoxide or aziridines were proposed based on the literatures and experimental results.
基金supported by the National Natural Science Foundation of China(Nos.52200186 and 52070025)Chongqing Natural Science Foundation(No.CSTB2024NSCQ-MSX0407)+1 种基金the National Key Research and Development Program of China(No.2019YFC1805502)Chongqing Municipal Human Resources and Social Security Bureau(No.2309013519935095).
文摘The organic pollutants,such as quaternary ammonium compounds,in high salinity flowback water from shale gas extraction may pose a severe risk to public health.Conventional biological technologies have limited effectiveness in the treatment of high-salt wastewaters,whereas electrocatalytic oxidation has shown potential for treating organic pollutants in high-salt flowback water.This study developed a carbon nanotubes(CNTs)doped Ru/Ir oxide coated Ti electrode CNTs-(Ru_(x)Ir_(y)O_(2))/Ti,which exhibited enhanced electrocatalytic performance for the treatment of quaternary ammonium compound in high-salt wastewater compared to the control metal oxide coated Ti anode(Ru_(x)Ir_(y)O_(2))/Ti,with pseudofirst-order reaction rate constant improved from 7.36×10^(-3) to 1.12×10^(-2) min−1.Moreover,the CNTs-(Ru_(x)Ir_(y)O_(2))/Ti anode electrocatalytic oxidation system exhibited excellent cycling stability.Mechanism studies indicated that the CNTs-(Ru_(x)Ir_(y)O_(2))/Ti electrode enhanced singlet oxygen(^(1)O_(2))generation,which played a major role in pollutant degradation.Furthermore,the formation of high concentrations of HClO and H_(2)O_(2) further facilitated the generation of ^(1)O_(2).This study may provide an efficient and green technology for the treatment of organic pollutants in high-salt shale gas flowback water.
基金supported by the National Key R&D Program of China(2021YFB3701100)the National Natural Science Foundation of China(52171101)the Fundamental Research Funds for the Central Universities(2024IAIS-QN009).
文摘Micro-arc oxidation(MAO)flm can only provide common mechanical protection for magnesium(Mg)–lithium(Li)alloys.These alloys are susceptible to severe localized corrosion,if the MAO flm is disrupted.This work reports the successful hydrothermal preparation of a MgLiAlCe-LDHs@GO flm on a MAO-coated Mg–Li alloy following Ce confnement.The graphene oxide(GO)sheet increased the difusion path of the corrosive media,and the addition of rare-earth cerium ions(Ce^(3+))endowed the flm with a certain self-healing ability,which signifcantly improved the corrosion resistance of the flm,and the corrosion current density(icorr)reached 3.27×10^(−8)A cm^(−2).The synergistic action of GO and Ce^(3+)can achieve long-term corrosion protection for the substrate.The corrosion resistance mechanism of MgLiAlCe-LDHs@GO flm was discussed by the scanning vibration electrode technique(SVET).
基金The research and development project of Beijing Disaster Prevention Technology Co.,Ltd.(FZKJYF202201)funded this work.
文摘Although the late Quaternary slip rate of the Northern Margin Fault of the Huaizhuo Basin(NFHB)was studied approximately 30 years ago using thermoluminescence and geomorphic methods,the underlying uncertainty cannot be neglected,considering the limitations resulting from age and displacement measurements.Accordingly,we attempted to re-estimate the late Quaternary slip rate of the NFHB using high-precision remote sensing image interpretation,large-scale geological and geomorphic mapping,paleoseismic analysis,and Quaternary geochronology testing.The results,based on stratigraphic dislocation and age constraint in the trenches,show that the present deformation of the NFHB has been dominated by the extension,with a vertical slip rate~0.04-0.11 mm/a.We estimate a vertical slip rate of~0.06 mm/a,with an R^(2) value of~0.91,which is much lower than the~0.5 mm/a result estimated previously.There are three possible reasons for this discrepancy.The first is the limitation resulting from dating and displacement measurements in earlier studies;the second is the slip decomposition caused by multiple branches of the NFHB,which leads to the low slip rate observed at a single fault;and third possible explanation is that the fault may be locked at present with a low slip rate,which means that the earthquake hazard of the NFHB cannot be ignored,and more in-depth research,such as geodetic and intensive observations of earthquake precursors,is urgently needed.This discovery poses a new challenge for the active study of the NFHB and the northeast corner of the Ordos Plateau in the North China Block.
文摘Ocean Drilling Program (ODP) Site 807A was recovered from the Ontong-Java plateau, western equatorial Pacific. Quantitative analysis of planktonic foraminifera, combined with oxygen and carbon isotope data, reveals the glacial-interglacial variations of sea-surface temperature and the upper water vertical structure in this region during the late Quaternary. Our results indicate that since 530 ka sea-surface temperature (SST) and the depth of thermocline (DOT) have changed significantly in the western Pacific warm pool (WPWP). The average glacial-interglacial annual SST difference was up to 4.2 ℃, and the DOT fluctuations could exceed more than 100 m, further suggesting the instability of the WPWP. The spectral analyses of SST and DOT reveal two dominating cyclicities—the typical 100 ka cycle and the semi-precessional cycle, which is significant in the tropical spectrum, indicating that late Quaternary paleoceanographic changes in the study area were influenced not only by a high latitude forcing but also by tropic-driving factors.
基金supported by the Chengdu University of Information Technology Doctoral Fund‘Study on the Initiation Mechanism of Hydraulic Debris Flow Based on Shields Stress’(KYTZ202275)the Second Tibetan Scientific Expedition and Research Program(Grant No.2019QZKK0902)。
文摘Debris flows have increased in frequency within the arid Daheba Basin on the northeastern Tibetan Plateau,but their sediment sources remain poorly quantified.Using high-resolution UAV-derived DEMs from 51 small catchments,this study evaluates the relative contributions of landslide-derived and channel-derived sediment in controlling debris-flow fan magnitude,and quantifies sediment supply during the 2023 rainy season using DEM differencing.A total of 766 landslides occurred predominantly on slopes of 40°-50°and southeast-southwest aspects,generating 36.17×10^(4)m^(3)of material.Gully heads exhibit exceptionally lower landscape dissection thresholds compared with loess and Quaternary regions in China,indicating high susceptibility to failure under intensified runoff.The results show that Landslide area-volume scaling exponent(b)varies with hillslope geometry(K_(u)):b>1.3 for K_(u)<8 and generally b<1.3 for K_(u)>8,indicating more complete scar evacuation upslope and partial erosion downslope.Despite the abundance of landslides,their contribution to debris flow fan magnitude is minor(<25%),with channel debris dominating(>75%).DEM differencing of a small catchment before and after the 2023 rainy season further reveals that sediment supply originates primarily from the main channel(60.6%)and tributaries(23.3%),with smaller contributions from channel banks(6.8%)and channel heads(9.2%).Tributaries exhibit the greatest mean erosion depth(4.2 m),exceeding that of the main channel(3.8 m).These findings demonstrate that debris-flow material supply in the Daheba Basin is transport-limited and controlled mainly by fluvial entrainment rather than slope failures.Climatic warming and wetting may enhance slope instability,but sediment mobilization is dominantly governed by runoff-driven channel erosion.This study underscores the importance of prioritizing channel sediment dynamics in debris flow hazards assessments for arid regions of the Tibetan plateau.
