LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)is an attractive material for high-energy-density Li-ion batteries in electric vehicles.However,it suffers from rapid capacity fading.Previous studies have shown that tuning the ...LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)is an attractive material for high-energy-density Li-ion batteries in electric vehicles.However,it suffers from rapid capacity fading.Previous studies have shown that tuning the positive electrode material via atomic layer deposition(ALD)can enhance the electrochemical performance of the material.In this article,we introduce a novel coating method using gaseous precursors in an ALD reactor,where an AlO_(x)layer is deposited directly on the surface of the NMC811 precursor,followed by lithiation.The AlO_(x)coating is applied to the NMC811 powder substrate by exposing it to gas-phase precursors,using a conventional ALD and simplified ALD(chemical vapor deposition-like)method.It is observed that the novel methods lead to the incorporation of Al as a dopant within the bulk of NMC811,rather than forming a conformal AlO_(x)coating,after the final lithiation step.The optimized procedures result in positive electrode materials with higher capacity and enhanced cycling stability in both half-cell and full-cell configurations.Doping or coating was shown to mitigate transition metal dissolution,reduce side reactions between the active material and electrolyte,and improve structural stability.展开更多
We demonstrate for the first time the critical influence of binder molecular weight on the performance of slurry-cast lithium nickel manganese cobalt oxide(NMC)cathodes in sulfide-based all-solid-state batteries(SSBs)...We demonstrate for the first time the critical influence of binder molecular weight on the performance of slurry-cast lithium nickel manganese cobalt oxide(NMC)cathodes in sulfide-based all-solid-state batteries(SSBs).SSBs are increasingly recognized as a safer and potentially more efficient alternative to traditional Li-ion batteries,owing to the superior ionic conductivities and inherent safety features of sulfide solid electrolytes.However,the integration of high-voltage NMC cathodes with sheet-type sulfide solid electrolytes presents significant fabrication challenges.Our findings reveal that higher molecular weight binders not only enhance the discharge capacity and cycle life of these cathodes but also ensure robust adhesion and structural integrity.By optimizing binder molecular weights,we effectively shield the active materials from degradation and mechanical stress,significantly boosting the functionality and longevity of SSBs.These results underscore the paramount importance of binder properties in advancing the practical application of high-performance all-solid-state batteries.展开更多
The position synchronization control(PSC) problem is studied for networked multi-axis servo systems(NMASSs) with time-varying delay that is smaller than one sampling period. To improve the control performance of the s...The position synchronization control(PSC) problem is studied for networked multi-axis servo systems(NMASSs) with time-varying delay that is smaller than one sampling period. To improve the control performance of the system, time-varying delays, modeling uncertainties, and external disturbances are first modeled as a lumped disturbance. Then, a linear extended state observer(LESO) is devised to estimate the system state and the lumped disturbance, and a linear feedback controller with disturbance compensation is designed to perform individual-axis tracking control. After that, a cross-coupled control approach is used to further improve synchronization performance. The bounded-input-bounded-output(BIBO) stability of the closedloop control system is analyzed. Finally, both simulation and experiment are carried out to demonstrate the effectiveness of the proposed method.展开更多
利用2012年6月12日—8月31日华中区域中尺度业务数值预报模式(WRF)一日两次的预报结果,采用NMC方法对背景误差协方差(B)进行了统计,得到了基于华中区域业务模式框架、分辨率和区域地理特征的夏季背景误差协方差矩阵的回归系数、特征向...利用2012年6月12日—8月31日华中区域中尺度业务数值预报模式(WRF)一日两次的预报结果,采用NMC方法对背景误差协方差(B)进行了统计,得到了基于华中区域业务模式框架、分辨率和区域地理特征的夏季背景误差协方差矩阵的回归系数、特征向量、特征值以及特征长度尺度,并对模式三重嵌套各区域B的统计结构特征进行了对比,结果表明不同区域B的统计结构特征差异明显,表明B与模式区域地理特征和分辨率等关系密切。为探讨不同B对模式预报的影响,采用WRF模式自带的通用B矩阵(CV3-B)及本文统计得到的本地化B矩阵两种方案对2013年6—8月进行了批量试验和统计检验,结果表明:采用本地化B后,24 h小雨、中雨、大雨和48 h中雨、大雨、暴雨降水预报TS评分皆有所提高。850 h Pa风、温度及2 m温度等要素场预报的均方根误差减小,但500 h Pa高度场均方根误差略有加大。暴雨个例的分析表明:不同B方案,对初值影响非常显著,本地化B方案分析的初值场更趋合理,因而改进了降水预报。展开更多
A CMOS （complementary metal-oxide-semiconductor transistor） low-dropout regulator （LDO） with 3. 3 V output voltage and 100 mA output current for system-on-chip applications to reduce board space and external pins ...A CMOS （complementary metal-oxide-semiconductor transistor） low-dropout regulator （LDO） with 3. 3 V output voltage and 100 mA output current for system-on-chip applications to reduce board space and external pins is presented. By utilizing a dynamic slew-rate enhancement（SRE） circuit and nested Miller compensation （NMC） on the LDO structure, the proposed LDO provides high stability during line and load regulation without off-chip load capacitors. The overshot voltage is limited within 550 mV and the settling time is less than 50 μs when the load current decreases from 100 mA to 1 mA. By using a 30 nA reference current, the quiescent current is 3.3 μA. The proposed design is implemented by CSMC 0. 5 μm mixed-signal process. The experimental results agree with the simulation results.展开更多
基金the European Union,the SOLiD project(grant agreement no.101069505),for the financial support。
文摘LiNi_(0.8)Mn_(0.1)Co_(0.1)O_(2)(NMC811)is an attractive material for high-energy-density Li-ion batteries in electric vehicles.However,it suffers from rapid capacity fading.Previous studies have shown that tuning the positive electrode material via atomic layer deposition(ALD)can enhance the electrochemical performance of the material.In this article,we introduce a novel coating method using gaseous precursors in an ALD reactor,where an AlO_(x)layer is deposited directly on the surface of the NMC811 precursor,followed by lithiation.The AlO_(x)coating is applied to the NMC811 powder substrate by exposing it to gas-phase precursors,using a conventional ALD and simplified ALD(chemical vapor deposition-like)method.It is observed that the novel methods lead to the incorporation of Al as a dopant within the bulk of NMC811,rather than forming a conformal AlO_(x)coating,after the final lithiation step.The optimized procedures result in positive electrode materials with higher capacity and enhanced cycling stability in both half-cell and full-cell configurations.Doping or coating was shown to mitigate transition metal dissolution,reduce side reactions between the active material and electrolyte,and improve structural stability.
基金partially sponsored by the Office of Energy Efficiency and Renewable Energy(EERE)in the Vehicle Technologies Office(VTO)through the Advanced Battery Materials Research(BMR)Program,managed by DrsThe Department of Energy will provide public access to these results of federally sponsored research in accordance with the DOE Public Access Plan(http://energy.gov/downloads/doe-public-access-plan).
文摘We demonstrate for the first time the critical influence of binder molecular weight on the performance of slurry-cast lithium nickel manganese cobalt oxide(NMC)cathodes in sulfide-based all-solid-state batteries(SSBs).SSBs are increasingly recognized as a safer and potentially more efficient alternative to traditional Li-ion batteries,owing to the superior ionic conductivities and inherent safety features of sulfide solid electrolytes.However,the integration of high-voltage NMC cathodes with sheet-type sulfide solid electrolytes presents significant fabrication challenges.Our findings reveal that higher molecular weight binders not only enhance the discharge capacity and cycle life of these cathodes but also ensure robust adhesion and structural integrity.By optimizing binder molecular weights,we effectively shield the active materials from degradation and mechanical stress,significantly boosting the functionality and longevity of SSBs.These results underscore the paramount importance of binder properties in advancing the practical application of high-performance all-solid-state batteries.
基金supported by the National Natural Science Foundation of China(NSFC)(61822311)the NSFC-Zhejiang Joint Fund for the Intergration of Industrialization and Informatization(U1709213)。
文摘The position synchronization control(PSC) problem is studied for networked multi-axis servo systems(NMASSs) with time-varying delay that is smaller than one sampling period. To improve the control performance of the system, time-varying delays, modeling uncertainties, and external disturbances are first modeled as a lumped disturbance. Then, a linear extended state observer(LESO) is devised to estimate the system state and the lumped disturbance, and a linear feedback controller with disturbance compensation is designed to perform individual-axis tracking control. After that, a cross-coupled control approach is used to further improve synchronization performance. The bounded-input-bounded-output(BIBO) stability of the closedloop control system is analyzed. Finally, both simulation and experiment are carried out to demonstrate the effectiveness of the proposed method.
文摘利用2012年6月12日—8月31日华中区域中尺度业务数值预报模式(WRF)一日两次的预报结果,采用NMC方法对背景误差协方差(B)进行了统计,得到了基于华中区域业务模式框架、分辨率和区域地理特征的夏季背景误差协方差矩阵的回归系数、特征向量、特征值以及特征长度尺度,并对模式三重嵌套各区域B的统计结构特征进行了对比,结果表明不同区域B的统计结构特征差异明显,表明B与模式区域地理特征和分辨率等关系密切。为探讨不同B对模式预报的影响,采用WRF模式自带的通用B矩阵(CV3-B)及本文统计得到的本地化B矩阵两种方案对2013年6—8月进行了批量试验和统计检验,结果表明:采用本地化B后,24 h小雨、中雨、大雨和48 h中雨、大雨、暴雨降水预报TS评分皆有所提高。850 h Pa风、温度及2 m温度等要素场预报的均方根误差减小,但500 h Pa高度场均方根误差略有加大。暴雨个例的分析表明:不同B方案,对初值影响非常显著,本地化B方案分析的初值场更趋合理,因而改进了降水预报。
基金The Key Science and Technology Project of Zhejiang Province(No.2007C21021)
文摘A CMOS （complementary metal-oxide-semiconductor transistor） low-dropout regulator （LDO） with 3. 3 V output voltage and 100 mA output current for system-on-chip applications to reduce board space and external pins is presented. By utilizing a dynamic slew-rate enhancement（SRE） circuit and nested Miller compensation （NMC） on the LDO structure, the proposed LDO provides high stability during line and load regulation without off-chip load capacitors. The overshot voltage is limited within 550 mV and the settling time is less than 50 μs when the load current decreases from 100 mA to 1 mA. By using a 30 nA reference current, the quiescent current is 3.3 μA. The proposed design is implemented by CSMC 0. 5 μm mixed-signal process. The experimental results agree with the simulation results.
